102162-49-2

Basic information

• Product Name: Benzenepropanol, carbonate (2:1)
• CAS NO: 102162-49-2
• Molecular Formula: C19H22O3
• Molecular Weight: 298.382
• Mol File: 102162-49-2.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzenepropanol, carbonate (2:1)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanol, carbonate (2:1)(102162-49-2)
• EPA Substance Registry System: Benzenepropanol, carbonate (2:1)(102162-49-2)

Safety Data

• Hazardous Substances Data: 102162-49-2(Hazardous Substances Data)

Upstream product

• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 170895-01-9 1-(3-phenylpropoxycarbonyl)-1H-imidazole 
• 122-97-4 3-Phenyl-1-propanol 
• 503-38-8 trichloromethyl chloroformate 
• 3742-75-4 3-phenylpropyl 4-methylbenzenesulfonate 
• 584-08-7 potassium carbonate 
• 104-52-9 phenylpropyl chloride 
• 637-59-2 1-Bromo-3-phenylpropane 
• 534-17-8 caesium carbonate 
• 530-62-1 1,1'-carbonyldiimidazole 
• 124-38-9 carbon dioxide 
• 69804-99-5 3-phenylpropanol methanesulfonate 
• 4119-41-9 1-iodo-3-phenylpropan 
• 6324-79-4 ethyl (3-phenylpropyl) carbonate 

Downstream Products

• 220579-83-9 <4-(3-<<6-(6-aminopurin-9-yl)-2,2-dimethyltetrahydrofuro<3,4-d><1,3>dioxol-4-ylmethyl>-amino>-propyl)-phenyl>-oxoacetic acid methyl ester 
• 220579-79-3 methyl <4-(3-hydroxypropyl)>-α-oxobenzeneacetate 
• 220579-80-6 methyl <4-(3-bromopropyl)>-α-oxobenzeneacetate 
• 220579-78-2 <3-<4'-(methyl)-2-oxoacetyl>phenyl>propylcarbonate 

Relevant articles and documents

Mechanistic insights into Br?nsted acid-induced nucleophilic substitution of aliphatic imidazole carbamate with halide ions

Herein we report interesting reactivity of imidazole carbamate towards nucleophilic substitution with halide ions under Br?nsted acidic conditions. Depending upon reaction conditions, halide ions could readily attack the carboxyl position and trigger decarboxylative alkyl halide formation. Alternatively, halide ions were also found to competitively undergo nucleophilic acyl substitution, which ultimately results in the generation of carbonate dimerization product.

Direct coupling of Cs2CO3 and alcohols for the synthesis of dimethyl, diethyl, and various dialkyl carbonates

-

Metal-Free Synthesis of Cyclic and Acyclic Carbonates from CO2 and Alcohols

Diverse cyclic and acyclic carbonates such as ethylene carbonate, propylene carbonate, glycerol carbonate, and dimethyl carbonate were synthesized in moderate to good yields by the direct coupling of the corresponding alcohols with carbon dioxide in the absence of metal catalysts and inorganic bases. The direct carbonation mechanism of alcohols in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene, 1-butyl-3-methylimidazolium hexafluorophosphate, and dibromomethane was probed by 18O-labeling experiments and chiral alcohol experiments. Diverse cyclic and acyclic carbonates were synthesized in moderate to good yields by the direct coupling of alcohols with carbon dioxide in the absence of metal catalysts and inorganic bases. The direct carbonation mechanism of alcohols in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) was probed by an 18O-labeling experiment and a chiral alcohol experiment.