102197-60-4

Basic information

• Product Name: phenylseleno 4-methyl(thiobenzoyl) sulfide
• Synonyms: phenylseleno 4-methyl(thiobenzoyl) sulfide
• CAS NO: 102197-60-4
• Molecular Weight: 307.275
• Mol File: 102197-60-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: phenylseleno 4-methyl(thiobenzoyl) sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: phenylseleno 4-methyl(thiobenzoyl) sulfide(102197-60-4)
• EPA Substance Registry System: phenylseleno 4-methyl(thiobenzoyl) sulfide(102197-60-4)

Safety Data

• Hazardous Substances Data: 102197-60-4(Hazardous Substances Data)

Upstream product

• 1666-13-3 diphenyl diselenide 
• 85156-89-4 4-methylbenzoylsulfenyl bromide 
• 23974-72-3 sodium phenylselenide 
• 60410-77-7 bis(4-methylbenzenethiocarbonyl) sulphide 
• 3335-25-9 4-methylthiobenzoyl chloride 
• 33861-17-5 phenyl trimethylsilyl selenide 
• 120449-42-5 Se-phenyl 4-methylbenzenecarboselenothioate 
• 71098-88-9 N-phenylselanylphthalimide 
• 50684-43-0 4-methylbenzothioic S-acid 

Downstream Products

• 77750-08-4 4-methylbenzenecarboselenoic acid Se-phenyl ester 

Relevant articles and documents

Se-Aryl Alkane- or Arenecarboselenothioates: Synthesis and Some Reactions

A series of Se-aryl carboselenothioates 3 (RCSSeAr, R=alkyl, aryl) were synthesized and characterized from the reaction of bis(thioacyl) sulfides 1 with sodium areneselenolates.The thionselenolesters 3 are stable (liquid or crystals) both thermally and to moisture.Reactions of 3 with aliphatic primary and secondary amines gave the corresponding ammonium carbodithioates 8 together with diphenyl diselenide 7.In contrast, treatment with aromatic amines or sodium alcoholates afforded the corresponding thioamides or O-alkyl or O-aryl thionoesters in good yields.The oxidation of 3 with m-chloroperbenzoic acid gave the corresponding sulfides 12 and acyl arylseleno sulfides 13 which are formed by a rearrangement of the ArSe group to the thiocarbonyl sulfur atom.

A convenient synthesis of S-acyl phenylselenosulfides

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