10220-33-4Relevant articles and documents
Organic reactions in ionic liquids: An efficient method for selective S-alkylation of 2-mercaptobenzothia(xa)zole with alkyl halides
Hu, Yi,Chen, Zhen-Chu,Le, Zhang-Gao,Zheng, Qin-Guo
, p. 2039 - 2046 (2004)
Ionic liquids based on 1-butyl-3-methylimidazolium hexafluorophosphate (BmimPF6) and 1-butyl-3-methylimidazolium tetrafluoroborate (BmimBF4) are used as reusable reaction medium in the selective S-alkylation of 2-mercaptobenzothia(xa)zole with alkyl halides in the presence of potassium carbonate. This procedure is convenient, efficient, and generally gives rise to the S-alkylated product exclusively.
Synthesis and application of new S-benzoheterocycle thiobenzoates photoinitiators
Zhao, Ziren,Wang, Chen,Liu, Feng,Zhang, Bianxiang
, p. 3717 - 3726 (2020/05/11)
A series of free radical photoinitiators with thioester bonds were synthesized by the nucleophilic substitution reaction of acyl chloride and thiol or thiophenol. These compounds could be efficiently obtained under mild reaction conditions and were fully
Selective approach to thioesters and thioethers via sp3 C-H activation of methylarenes
Feng,Lu,Cai
, p. 54409 - 54415 (2015/01/16)
Novel C-S cross-dehydrogenative coupling (CDC) approaches for the selective synthesis of thioesters and thioethers have been developed via sp3 C-H activation of methylarenes and subsequent functionalization. The reaction of methylarenes with thiols resulted in thioesters in the presence of a FeBr2/TBHP system, while treatment of methylarenes with thiols in the Pd(OAc)2/O2/TBHP system led to the formation of thioethers. Both the green protocols demonstrate good functional group tolerance and satisfactory yields. This journal is