102235-57-4

Basic information

• Product Name: 3,4,5-Tri-O-benzyl-2,6-didesoxy-D-ribo-aldehydo-hexose
• Synonyms: 3,4,5-Tri-O-benzyl-2,6-didesoxy-D-ribo-aldehydo-hexose
• CAS NO: 102235-57-4
• Molecular Weight: 418.533
• Mol File: 102235-57-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3,4,5-Tri-O-benzyl-2,6-didesoxy-D-ribo-aldehydo-hexose(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,5-Tri-O-benzyl-2,6-didesoxy-D-ribo-aldehydo-hexose(102235-57-4)
• EPA Substance Registry System: 3,4,5-Tri-O-benzyl-2,6-didesoxy-D-ribo-aldehydo-hexose(102235-57-4)

Safety Data

• Hazardous Substances Data: 102235-57-4(Hazardous Substances Data)

Upstream product

• 102235-50-7 4-O-Benzyl-DL-erythro-1,5-hexadien-3,4-diol 
• 102235-51-8 1,2-Anhydro-4-O-benzyl-5,6-didesoxy-L-ribo-hex-5-enitol 
• 102235-55-2 2,3,4-Tri-O-benzyl-1,5,6-tridesoxy-L-ribo-hex-5-enitol 
• 102235-54-1 4-O-Benzyl-1,5,6-tridesoxy-L-ribo-hex-5-enitol 
• 100-39-0 benzyl bromide 
• 1256091-53-8 meso-1,5-hexadiene-3,4-diol 
• 2053-00-1 D-digitoxose 
• 13051-82-6 2,6-dideoxy-D-ribo-hexose diethyl dithioacetal 
• 527-52-6 D-digitxose 
• 291282-23-0 C₃₁H₄₀O₃S₂ 
• 102235-56-3 3,4,5-Tri-O-benzyl-2,6-didesoxy-D-ribo-hexitol 

Downstream Products

• 258348-49-1 (3S,4R,5R)-3,4,5-Tris-benzyloxy-hexanoic acid 

Relevant articles and documents

A general route to 4-C-branched sugars. Synthesis of methyl α-caryophylloside

The total synthesis of methyl 3,6-dideoxy-4-C-(D-altro-1,3,4,5 tetrahydroxyhexyl)-α-D-xylo-hexopyranoside, the methyl glycoside of the recently isolated 4-C-branched sugar caryophyllose, has been completed in a stereoselective and convergent manner. The synthesis of this dodecose relies on the diiodosamarium mediated coupling of two six-carbon fragments: a cyclic ketone and an acid chloride.

De novo Synthesis of Carbohydrates and Related Natural Products, 22. - Synthesis of D-Digitoxose from meso-Divinylglycol

Selective monobenzylation of meso- and rac-divinylglycol (2-m and 2-d,l) affords racemates (+/-)-8 and (+/-)-10, respectively; they are transferred with the help of the Sharpless method under kinetic racemate resolution diastereoselectively into the enant