1022913-39-8Relevant articles and documents
Vanadium-catalyzed cross-coupling reactions of alkyl halides with aryl grignard reagents
Yasuda, Shigeo,Yorimitsu, Hideki,Oshima, Koichiro
, p. 287 - 290 (2008)
Vanadium(III) chloride catalyzed cross-coupling reactions of alkyl halides with arylmagnesium bromides. Various arylmagnesium bromides, except for an ortho-substituted arylmagnesium reagent, could be used for the reaction. Among alkyl halides tested, cyclohexyl halides and primary alkyl halides were good substrates. The reactions likely proceed via carbon-centered radical intermediates. 2008 The Chemical Society of Japan.
Nickel-catalyzed cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl grignard reagents using (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene as ligand
Kanemura, Shigenari,Kondoh, Azusa,Yorimitsu, Hideki,Oshima, Koichiro
scheme or table, p. 2659 - 2664 (2009/04/05)
A combination of nickel(II) acetylacetonate and (Z)-3,3-dimethyl-1,2- bis(diphenylphosphino)but-1-ene catalyzes cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with alkyl Grignard reagents. Not only primary but also secondary alkyl Grignard reagents can be employed. Georg Thieme Verlag Stuttgart.