1023310-53-3

Basic information

• Product Name: 2,3,4,5-tetra-O-benzyl-1,6-di-O-trityl-D-glucitol
• Synonyms: 2,3,4,5-tetra-O-benzyl-1,6-di-O-trityl-D-glucitol
• CAS NO: 1023310-53-3
• Molecular Weight: 1027.31
• Mol File: 1023310-53-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,3,4,5-tetra-O-benzyl-1,6-di-O-trityl-D-glucitol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,5-tetra-O-benzyl-1,6-di-O-trityl-D-glucitol(1023310-53-3)
• EPA Substance Registry System: 2,3,4,5-tetra-O-benzyl-1,6-di-O-trityl-D-glucitol(1023310-53-3)

Safety Data

• Hazardous Substances Data: 1023310-53-3(Hazardous Substances Data)

Upstream product

• 76-83-5 trityl chloride 
• 29780-95-8 1,6-di-O-trityl-D-glucitol 
• 100-39-0 benzyl bromide 
• 50-70-4 D-sorbitol 
• 98-88-4 benzoyl chloride 

Downstream Products

• 256342-72-0 2,3,4,5-tetrakis-benzyloxyhexane-1,6-diol 
• 1607827-84-8 (2S,3S,4R,5R,6R)-2,3,4,5-tetrakis(benzyloxy)-6-hydroxycyclohexanone 
• 1607827-85-9 (2S,3S,4S,5S,6R)-6-acetoxy-2,3,4,5-tetrakis(benzyloxy)-cyclohexanone 
• 1607827-90-6 (2S,3S,4R,5S,6R)-2,3,4,5-tetrakis(benzyloxy)-6-hydroxycyclohexanone 
• 1607827-91-7 (2S,3S,4S,5R,6R)-6-acetoxy-2,3,4,5-tetrakis(benzyloxy)-cyclohexanone 
• 1607827-97-3 (1R,2S,3R,4R,5R,6R)-3,4,5,6-tetrakis(benzyloxy)cyclohexane-1,2-diol 
• 195873-70-2 (3R,4R,5R,6S)-3,4,5,6-tetra(benzoyloxy)-1,7-octadiene 
• 277744-76-0 2,3,4,5-tetra-O-benzyl-D-gluco-hexodialdose 
• 224433-58-3 (3R,4R,5R,6S)-3,4,5,6-tetra(benzyloxy)-cyclohexene 

Relevant articles and documents

Synthesis of allo - And epi -inositol via the NHC-catalyzed carbocyclization of carbohydrate-derived dialdehydes

A synthesis of carbocyclic sugars from carbohydrate-derived dialdehydes using organocatalysis has been developed. Sorbitol, mannitol, and galactitol were converted via 1,6-tritylation, perbenzylation or permethylation, detritylation, and Swern oxidation into 2,3,4,5-tetra-O-alkyl-dialdoses that were cyclized via the benzoin reaction promoted by a triazolium carbene. Manno- and galacto-configured dialdehydes gave predominantly single inosose stereoisomers in up to 75% yield if the mixture was acetylated prior to isolation while the gluco-dialdehyde afforded a mixture of three stereoisomers in 61% overall yield. The inososes were stereospecifically reduced using sodium borohydride and then deprotected to give allo- and epi-inositol in good yield that confirmed the structural and stereochemical assignments.

A straightforward synthesis of perbenzylated conduritols from alditols by ring closing olefin metathesis

The synthesis of perbenzylated conduritols A, E and F has been achieved in six steps by formal conversion of galactitol, D-mannitol and D-glucitol into the respective terminal dienes, followed by ring closing olefin metathesis. The Royal Society of Chemistry 1999.