10234-40-9Relevant articles and documents
Azo and azoxythiacrown ethers: Synthesis and properties
Kertmen, Ahmet,Szczygelska-Tao, Jolanta,Chojnacki, Jaros?aw
, p. 10662 - 10668 (2013)
A series of 16- and 18-membered azo- and azoxythiacrown ethers have been synthesized by reductive macrocyclization of the respective bis(nitrophenoxy) oxaalkanes. The aromatic residues located in the polyether region of the molecule were introduced to mac
STUDIES IN THE CROWN ETHER SERIES. 3. CATALYTIC ACTIVITY OF CROWN ETHERS AND THEIR "HETEROGENATED" ANALOGS
Abakumova, N. I.,Kolenko, I. P.,Petrov, L. A.,Novoselova, A. A.,Gus'kova, L. M.
, p. 126 - 128 (1988)
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Copper(ii) and cobalt(ii) complexes based on bis-benzimidazolyl ligand with 1,2-bis(2′-ethoxy)phenyl linker: Synthesis, crystal structure and conformations
Liu, Qing-Xiang,Bi, Yue,Zhao, Xiao-Jun,Zhao, Zhi-Xiang,Wang, Jian-Hua,Wang, Xiu-Guang
, p. 1950 - 1962 (2014)
Seven Cu(ii) and Co(ii) complexes [Co(L)2(H2O) 2]Cl2 (1), [Cu(L)Cl2]2 (2), [Cu(L)(NO3)2]2 (3), [Cu(L)(SO 4)]2 (4), [Co(L)(LA/sub
Revisiting Hydroxyalkylation of Phenols with Cyclic Carbonates
Kao, Shih-Chieh,Lin, Yi-Ching,Ryu, Ilhyong,Wu, Yen-Ku
supporting information, p. 3639 - 3644 (2019/07/10)
Described is a tetrabutylammonium fluoride-mediated hydroxyalkylation reaction of phenols with cyclic carbonates. This operationally simple method enables the synthesis of a variety of aryl β-hydroxyethyl ethers in good to excellent yields with a very small amount of catalyst loading (0.1–1 mol%). Of particular note is the efficient conversion of aromatic diols and phloroglucinol to the corresponding bis- and tris-hydroxyethylated products. To further showcase the versatility of this protocol, guaifenesin was prepared with a single step by the condensation of guaiacol and glycerol carbonate. We also developed a flow ethoxylation process permitting the continuous synthesis of multiflorol. (Figure presented.).