102474-59-9

Basic information

• Product Name: Benzeneethanamine, N-methyl-N,a-diphenyl-
• CAS NO: 102474-59-9
• Molecular Formula: C21H21N
• Molecular Weight: 287.404
• Mol File: 102474-59-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzeneethanamine, N-methyl-N,a-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneethanamine, N-methyl-N,a-diphenyl-(102474-59-9)
• EPA Substance Registry System: Benzeneethanamine, N-methyl-N,a-diphenyl-(102474-59-9)

Safety Data

• Hazardous Substances Data: 102474-59-9(Hazardous Substances Data)

Upstream product

• 131916-59-1 N,N-dibenzyl-N-methyl-anilinium; iodide 
• 501-65-5 diphenyl acetylene 
• 100-61-8 N-methylaniline 

Relevant articles and documents

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Tin-Catalyzed Selective Reductive Hydroamination of Alkynes for the Synthesis of Tertiary Amines

A unique preference of tin(II) for aniline activation is disclosed. In the present work tin(II) triflate-catalyzed highly selective Markovnikov reductive hydroamination of internal as well as terminal alkynes is reported. The mechanistic study revealed the involvement of two steps in one pot wherein alkyne reduces to corresponding alkene in presence of PMHS as reducing agent followed by hydroamination of alkene. A broad range of alkynes transformed into tertiary amines with good to excellent yield. This method is equally applicable in synthesis of secondary amines.