102503-45-7

Basic information

• Product Name: (Z)-2-Phenyl-2-(trimethylsiloxy)ethanaloxim-O-trimethylsilylether
• CAS NO: 102503-45-7
• Molecular Weight: 295.529
• Mol File: 102503-45-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-2-Phenyl-2-(trimethylsiloxy)ethanaloxim-O-trimethylsilylether(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2-Phenyl-2-(trimethylsiloxy)ethanaloxim-O-trimethylsilylether(102503-45-7)
• EPA Substance Registry System: (Z)-2-Phenyl-2-(trimethylsiloxy)ethanaloxim-O-trimethylsilylether(102503-45-7)

Safety Data

• Hazardous Substances Data: 102503-45-7(Hazardous Substances Data)

Upstream product

• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 6125-24-2 2-Phenylnitroethane 

Relevant articles and documents

Reactions of Trialkylsilyl Trifluoromethanesulfonates, IV. - 1,3-Trialkylsiloxy Shift - a New Rearrangement Reaction During the Silylation of Nitroalkanes

Nitroalkanes 1 with C-H bonds in β-position react with two-fold molar amounts of trialkylsilyl triflates 2 in the presence of triethylamine to yield 2-(trialkylsiloxy)oxime O-trialkylsilyl ethers 5 by 1,3-trialkylsiloxy shift.Oxime ethers 5 are also obtai