102513-02-0

Basic information

• Product Name: Mn(CO)4(Br)P(C₆H₅)2Si(CH₃)3
• CAS NO: 102513-02-0
• Molecular Weight: 505.259
• Mol File: 102513-02-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Mn(CO)4(Br)P(C₆H₅)2Si(CH₃)3(CAS DataBase Reference)
• NIST Chemistry Reference: Mn(CO)4(Br)P(C₆H₅)2Si(CH₃)3(102513-02-0)
• EPA Substance Registry System: Mn(CO)4(Br)P(C₆H₅)2Si(CH₃)3(102513-02-0)

Safety Data

• Hazardous Substances Data: 102513-02-0(Hazardous Substances Data)

Upstream product

• 14516-54-2 bromopentacarbonylmanganese(I) 
• 17154-34-6 (trimethylsilyl)diphenylphosphine 

Relevant articles and documents

Reactions of Silylphosphanes with Halogeno Complexes of Transition Metals: Synthesis, Structure and Properties of Complexes cis-X(CO)4Mn3-n(SiMe3)n> (n = 1-3), 2PPhR>X (R = Ph, H) and 3PH>X (X = Cl, Br, I)

The reactions of pentacarbonylmanganese halides (CO)5MnX (X = Cl, Br, I) with the silylphosphanes Ph3-nP(SiMe3)n (n = 1-3) at ambient temperature result in the elimination of one CO ligand and the formation of cis-configurated substitution products X(CO)4Mn3-n(SiMe3)n>.No CO-substitution, but Me3SiX-elimination is observed in the reaction of Ph3-nP(SiMe3)n with the dicarbonylcyclopentadienyliron halides CpFe(CO)2X to give the di- and triferriophosphonium halides 2PPhR>X (R = Ph, H) and 3PH>X (X = Cl, Br, I).The mass, IR and NMR spectra are reported and discussed.The crystal structures of cis-I(CO)4MnPPh2SiMe3 and 2PPh2>I have been determined. - Keywords: Trimethylsilyl Phosphanes, Substitution Reactions, Tetracarbonylhalogenomanganese Complexes, Halogenosilane Elimination, IR Spectra.