102615-56-5

Basic information

• Product Name: 2-(dimethylamino)-α-(trimethylsilyl)toluene
• Synonyms: 2-(dimethylamino)-α-(trimethylsilyl)toluene
• CAS NO: 102615-56-5
• Molecular Weight: 207.391
• Mol File: 102615-56-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(dimethylamino)-α-(trimethylsilyl)toluene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(dimethylamino)-α-(trimethylsilyl)toluene(102615-56-5)
• EPA Substance Registry System: 2-(dimethylamino)-α-(trimethylsilyl)toluene(102615-56-5)

Safety Data

• Hazardous Substances Data: 102615-56-5(Hazardous Substances Data)

Upstream product

• 27199-13-9 bis(diethyl sulfide)palladium dichloride 

Downstream Products

• 1445712-99-1 1-(2-(dimethylamino)phenyl)hexan-2-ol 
• 1445712-90-2 (E)-1-(2-(dimethylamino)phenyl)-4-phenylbut-3-en-2-ol 
• 1445712-88-8 1-(4-bromophenyl)-2-(2-(dimethylamino)phenyl)ethanol 

Relevant articles and documents

Michael Adducts of (Alkynylcarbene)pentacarbonylchromium Complexes: Formation, Stereochemistry, and Thermal Rearrangement

β-Donor-substituted α,β-unsaturated chromium carbene complexes (CO)5CrC(OEt)C=CR(XR'n) (X = N, O, S; 3, 9, 11-16, 22-25) have been synthesized by Michael addition of amines, alcohols, and thiols to alkynylcarbene complexes (CO)5CrC(OEt)C=-CR (1).The configurations of the newly formed C-C double bonds have been determined by NOE/NOESY measurements and X-ray crystal structure analysis.These vinylcarbene complexes lose one carbonyl ligand in refluxing tetrahydrofuran to give tetracarbonyl complexes (CO)4CrC(OEt)C=CR(XR'n) (X = N, O, S; 26-28). Key Words: Chromium, alkynylcarbene complexes / Vinylcarbenechromium complexes, β-donor-substituted / Carbene complexes, vinyl chelated