10264-22-9

Basic information

• Product Name: N-hexyl-3-phenylpropionamide
• Synonyms: N-hexyl-3-phenylpropionamide
• CAS NO: 10264-22-9
• Molecular Weight: 233.354
• Mol File: 10264-22-9.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: N-hexyl-3-phenylpropionamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-hexyl-3-phenylpropionamide(10264-22-9)
• EPA Substance Registry System: N-hexyl-3-phenylpropionamide(10264-22-9)

Safety Data

• Hazardous Substances Data: 10264-22-9(Hazardous Substances Data)

Upstream product

• 111-26-2 hexan-1-amine 
• 122-97-4 3-Phenyl-1-propanol 
• 100-42-5 styrene 
• 201230-82-2 carbon monoxide 
• 501-52-0 3-Phenylpropionic acid 
• 103-25-3 3-phenylpropanoic acid methyl ester 
• 463298-63-7 (S)-(2,3,4,5,6-pentafluorophenyl) 3-phenylpropanethioate 
• 40123-57-7 (2,3,4,5,6-pentafluorophenyl) 3-phenylpropanoate 
• 645-45-4 hydrocinnamic acid chloride 
• 3538-68-9 3-phenylpropanehydrazide 

Relevant articles and documents

Phototriggered Active Alkyne Generation from Cyclopropenones with Visible Light-Responsive Photocatalysts

A photocatalytic active alkyne generation reaction was developed using cyclopropenone as a starting reagent. Visible light-responsive photocatalysts induced cyclopropenone decarbonylation. The resulting highly reactive alkyne could be used directly, witho

Ammonia-borane as a Catalyst for the Direct Amidation of Carboxylic Acids

Ammonia-borane serves as an efficient substoichiometric (10%) precatalyst for the direct amidation of both aromatic and aliphatic carboxylic acids. In situ generation of amine-boranes precedes the amidation and, unlike the amidation with stoichiometric amine-boranes, this process is facile with 1 equiv of the acid. This methodology has high functional group tolerance and chromatography-free purification but is not amenable for esterification. The latter feature has been exploited to prepare hydroxyl- and thiol-containing amides.

Studies of the Electronic Effects of Zinc Cluster Catalysts and Their Application to the Transesterification of β-Keto Esters

The electronic effects of tetranuclear zinc cluster catalysts on transesterification were investigated by changing the carboxylate ligands in the clusters. High catalyst activity crucially depended on the balance between Lewis acidity and Br?nsted basicity of the catalyst; this was consistent with the dual activation of both the electrophile and nucleophile by the cooperative zinc centers. In addition, tetranuclear zinc cluster catalysts achieved the transesterification of β-keto esters with unprecedented levels of broad substrate generality, in which a newly developed pentafluoropropionate-bridged zinc cluster and 4-dimethylaminopyridine additive greatly improved the reactivity of sterically congested α- and α,α-disubstituted β-keto esters. Lewis versus Br?nsted: High catalyst activity of zinc clusters on transesterification crucially depend on a balance between Lewis acidity and Br?nsted basicity of the catalyst. Zinc clusters, including a newly developed pentafluoropropionate-bridged zinc cluster, achieved the transesterification of β-keto esters with unprecedented levels of broad substrate generality (see figure).