1026489-01-9

Basic information

• Product Name: tert-Butyl-[((E)-hexadec-5-enyl)oxy]-diphenyl-silane
• CAS NO: 1026489-01-9
• Molecular Weight: 478.834
• Mol File: 1026489-01-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-Butyl-[((E)-hexadec-5-enyl)oxy]-diphenyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl-[((E)-hexadec-5-enyl)oxy]-diphenyl-silane(1026489-01-9)
• EPA Substance Registry System: tert-Butyl-[((E)-hexadec-5-enyl)oxy]-diphenyl-silane(1026489-01-9)

Safety Data

• Hazardous Substances Data: 1026489-01-9(Hazardous Substances Data)

Upstream product

• 4221-03-8 5-hydroxypentanal 
• 542-28-9 3,4,5,6-tetrahydro-2H-pyran-2-one 
• 60669-22-9 n-undecyltriphenylphosphonium bromide 
• 131216-47-2 5-(tert-butyldiphenylsilyloxy)pentanal 

Downstream Products

• 89102-36-3 (5R,6S)-6-hydroxyhexadecan-5-olide 
• 7056-84-0 (E)-5-Hexadecenoic acid 

Relevant articles and documents

A general synthetic route towards γ- and δ-lactones. Total asymmetric synthesis of (-)-muricatacin and the mosquito oviposition pheromone (5R, 6s)- 6-acetoxy-hexadecanolide

Five (or six) membered asymmetric lactones are synthesized from γ- butyrolactone (or δ-valerolactone) in a straightforward way using the following reaction sequence: reduction, Wittig-Schlosser coupling, Sharpless asymmetric dihydroxylation, oxidation and lactonization. Thus, (-)muricatacin is synthesized in six steps (43% overall yield). Furthermore, (5R,6S)-6- acetoxy-hexadecanolide is prepared in eight steps (38% overall yield) via a carbonate ester, utilizing a novel lactonization with inversion of stereochemistry.