102714-45-4

Basic information

• Product Name: methyl (2Z)-2-benzoyl-3-phenyl-2-propenoate
• Synonyms: methyl (2Z)-2-benzoyl-3-phenyl-2-propenoate
• CAS NO: 102714-45-4
• Molecular Weight: 266.296
• Mol File: 102714-45-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: methyl (2Z)-2-benzoyl-3-phenyl-2-propenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (2Z)-2-benzoyl-3-phenyl-2-propenoate(102714-45-4)
• EPA Substance Registry System: methyl (2Z)-2-benzoyl-3-phenyl-2-propenoate(102714-45-4)

Safety Data

• Hazardous Substances Data: 102714-45-4(Hazardous Substances Data)

Upstream product

• 2538-76-3 1,1'-benzylidenedipiperidine 
• 455-32-3 benzoyl fluoride 
• 4891-38-7 phenylpropynoic acid methyl ester 
• 2622-14-2 tricyclohexylphosphine 
• 100-52-7 benzaldehyde 
• 103-26-4 Methyl cinnamate 
• 38855-09-3 methyl 3-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-3-phenylpropanoate 
• 890660-73-8 methyl 2-benzoyl-3-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-3-phenylpropanoate 
• 102714-54-5 methyl 2-benzoyl-3-phenyl-3-piperidinopropionate 
• 102714-53-4 methyl 2-benzoyl-3-pyrrolidino-3-pheylpropionate 
• 614-27-7 methyl 3-oxo-3-phenylpropionate 

Downstream Products

• 83303-48-4 1-Oxo-3-phenyl-indan-2-carboxylic acid methyl ester 

Relevant articles and documents

Phosphine-Catalyzed Intermolecular Acylfluorination of Alkynes via a P(V) Intermediate

We report the phosphine-catalyzed intermolecular carbofluorination of alkynes using acyl fluorides as fluorinating reagents. This reaction promises to be a useful method for the synthesis of highly substituted monofluoroalkene derivatives since acyl fluor

Three-step α-acylation of (E)-cinnamate esters with inversion of stereochemistry through formation and cleavage of carbon- pentamethylcyclopentadienyl bonds

The reaction of cinnamate esters with lithium pentamethylcyclopentadienide in the presence of chlorodiethylaluminum provides the corresponding 1,4-adducts in high yield. The adducts undergo α-acylation reaction upon treatment with lithium diisopropylamide

STEREOCHEMISTRY OF AMINE-CATALYZED KNOEVENAGEL REACTIONS

The amine-catalyzed Knoevenagel reactions of aldehydes and active methylene compounds containing two activating groups were found to involve many reversible steps, and the diastereomeric intermediary condensation compounds yielded thermodynamically stable products via carbanionic intermediates stablized and sterically affected by two activating groups.