10273-87-7

Basic information

• Product Name: 1,1'-Biphenyl, 2,2',6-trimethyl-
• CAS NO: 10273-87-7
• Molecular Formula: C15H16
• Molecular Weight: 196.292
• Mol File: 10273-87-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,1'-Biphenyl, 2,2',6-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-Biphenyl, 2,2',6-trimethyl-(10273-87-7)
• EPA Substance Registry System: 1,1'-Biphenyl, 2,2',6-trimethyl-(10273-87-7)

Safety Data

• Hazardous Substances Data: 10273-87-7(Hazardous Substances Data)

Upstream product

• 6781-98-2 2,6-dimethyl-1-chlorobenzene 
• 16419-60-6 2-Methylphenylboronic acid 
• 95-49-8 2-methylchlorobenzene 
• 100379-00-8 2,6-dimethylbenzene boronic acid 
• 576-22-7 2-Bromo-m-xylene 
• 108-38-3 m-xylene 
• 95-53-4 o-toluidine 

Relevant articles and documents

The Suzuki coupling of aryl chlorides under microwave heating

Simple, inexpensive catalysts formed in situ from tricyclohexylphosphine and palladium acetate or a phosphite-based palladacycle show unprecedented activity in the Suzuki coupling of deactivated, non-activated and activated aryl chloride substrates under microwave heating.

Sterically demanding, water-soluble alkylphosphines as ligands for high activity Suzuki coupling of aryl bromides in Aqueous solvents

(Equation presented) Sterically demanding, water-soluble alkylphosphines have been found to give highly active catalysts for Suzuki coupling of aryl bromides in aqueous solvents. A variety of aryl bromides and boronic acids were coupled in excellent yield

PREPARATION OF SOME TRIMETHYL- AND METHYLETHYLBIPHENYLS AND REACTIVITY OF AROMATIC HYDROCARBONS IN THE GOMBERG REACTION

Trimethyl- and methylethylbiphenyls with the alkyl groups in the both phenyl rings have been prepared by the Gomberg reaction and identified by the capillary gas-liquid chromatography.Depending on choice of the aromatic hydrocarbon either individual isomers or their mixtures (three at the most) have been obtained which were contaminated with compounds of diarylmethane type in many cases.The methylethylbiphenyls have only been prepared as mixtures contaminated with diarylmethanes.These side products have been prepared by independent syntheses.A method has been developed for isolation and separation of mixtures of trimethyl- and methylethylbiphenyls from the reaction products containing tarry products.The method is suitable for preparation of small amounts of some analytical standards.The HMO method has been used for calculation of values of the radical superdelocalizabilities at individual centres in the molecules of o-, m- and p-xylene, toluene and ethylbenzene, and these values have been compared with composition of the Gomberg reaction products from these hydrocarbons.The competitive technique has been used for comparison of the reactivities of the mentioned aromatic substrates in the Gomberg reactions.