102786-83-4

Basic information

• Product Name: [(Dichloro-fluoro-methylsulfanyl)-(diisopropoxy-phosphoryl)-methyl]-phosphonic acid diisopropyl ester
• Synonyms: [(Dichloro-fluoro-methylsulfanyl)-(diisopropoxy-phosphoryl)-methyl]-phosphonic acid diisopropyl ester
• CAS NO: 102786-83-4
• Molecular Weight: 477.299
• Mol File: 102786-83-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(Dichloro-fluoro-methylsulfanyl)-(diisopropoxy-phosphoryl)-methyl]-phosphonic acid diisopropyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [(Dichloro-fluoro-methylsulfanyl)-(diisopropoxy-phosphoryl)-methyl]-phosphonic acid diisopropyl ester(102786-83-4)
• EPA Substance Registry System: [(Dichloro-fluoro-methylsulfanyl)-(diisopropoxy-phosphoryl)-methyl]-phosphonic acid diisopropyl ester(102786-83-4)

Safety Data

• Hazardous Substances Data: 102786-83-4(Hazardous Substances Data)

Upstream product

• 1660-95-3 Tetraisopropyl methylenediphosphonate 
• 2712-93-8 dichlorofluoromethanesulphenyl chloride 

Relevant articles and documents

Ttrihalogenomethylsulphenylation of Tetraisopropyl Methylenebisphosphonates

Trihalogenomethylthiomethylenebisphosphonates, 2CRSCClnF(3-n) (n = 0-2; R = H, Me), are formed by reaction of salts of tetraisopropyl methylenebisphosphonates, 2CRM (M = Li, Na; R = H, Me), with trihalogenomethanesulphenyl chlorides, CClnF(3-n)SCl (n = 0-2).The ester products are transesterified with bromotrimethylsilane and hydrolysed with aqueous methanolic sodium hydroxide to give the corresponding tetrasodium salts of the bisphosphonic acids.The sulphenylation reactions are complex and are facilitated by the use of Lewis acids.Sulphenylations using chlorodifluoro- and dichloro-methanesulphenyl chlorides afford unexpected additional produts arising from chlorine replacement by fluorine.