1028292-91-2

Basic information

• Product Name: diethyl bis(2,5-dimethoxybenzyl)malonate
• Synonyms: diethyl bis(2,5-dimethoxybenzyl)malonate
• CAS NO: 1028292-91-2
• Molecular Weight: 460.524
• Mol File: 1028292-91-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diethyl bis(2,5-dimethoxybenzyl)malonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl bis(2,5-dimethoxybenzyl)malonate(1028292-91-2)
• EPA Substance Registry System: diethyl bis(2,5-dimethoxybenzyl)malonate(1028292-91-2)

Safety Data

• Hazardous Substances Data: 1028292-91-2(Hazardous Substances Data)

Upstream product

• 3840-27-5 2,5-dimethoxybenzyl chloride 
• 105-53-3 diethyl malonate 

Downstream Products

• 252190-36-6 bis(2,5-dimethoxybenzyl)malonyl chloride 
• 252190-33-3 bis(2,5-dimethoxybenzyl)malonic acid 

Relevant articles and documents

Synthesis, structure, and nucleophile-induced rearrangements of spiroketones

Three tetraketones based on the 2,2'-spirobiindan-1,1',3,3'-tetraone skeleton were prepared and investigated. All three compounds show spiroconjugation between their perpendicular π-networks. The interaction results in lowering of the energy of the LUMO of the systems by ca. 0.2-0.3 eV as compared to non-spiroconjugated models. The spiroketones are susceptible to nucleophile-induced retro-Claisen condensations that lead to molecular rearrangements destroying spiro connectivity.