1028667-77-7Relevant articles and documents
Polytypism, homochirality, interpenetration, and hydrogen-bonding in transition metal (Mn(II), Ni(II), Cu(II), Zn(II)) 5-hydroxyisophthalate coordination polymers containing 4,4′-bipyridyl
Feller, Russell K.,Cheetham, Anthony K.
, p. 2034 - 2042 (2008)
We report the synthesis of five coordination polymers of divalent transition metals combined with 5-hydroxyisophthalic acid (HIP) and 4,4′-bipyridyl (bipy). Mn forms two polytypic two-dimensional coordination polymers, Mn(HIP)(bipy)?3H2O and Mn(HIP)(bipy)?1/ 4bipy?2H2O (I and II, with ABAB and ABC stacking sequences, respectively); Ni forms a chiral hexagonal three-dimensional coordination polymer with two interpenetrating trigonal sublattices exhibiting the dual quartz topology, Ni(HIP)(bipy)(H2O) (III); Cu forms a one-dimensional coordination polymer containing arrays of infinite hydrogen-bonded molecular ribbons, Cu(HIP)2(bipy) (IV); and Zn forms a two-dimensional coordination polymer with a stair-stepped layered structure, Zn2(HIP)2(bipy)(H2O)2?H 2O (V). The M-HIP-M connections are perpendicular to the M-bipy-M connections in all structures where they are present. The Royal Society of Chemistry.