102879-13-0Relevant articles and documents
Efficient conversion of alkenes to chlorohydrins by a Ru-based artificial enzyme
Lopez, Sarah,Rondot, Laurianne,Cavazza, Christine,Iannello, Marina,Boeri-Erba, Elisabetta,Burzlaff, Nicolai,Strinitz, Frank,Jorge-Robin, Adeline,Marchi-Delapierre, Caroline,Ménage, Stéphane
, p. 3579 - 3582 (2017)
Artificial enzymes are required to catalyse non-natural reactions. Here, a hybrid catalyst was developed by embedding a novel Ru complex in the transport protein NikA. The protein scaffold activates the bound Ru complex to produce a catalyst with high regio- and stereo-selectivity. The hybrid efficiently and stably produced α-hydroxy-β-chloro chlorohydrins from alkenes (up to 180 TON with a TOF of 1050 h?1).
1,2-Ferrocenediylazaphosphinines 2: A new class of nucleophilic catalysts for ring-opening of epoxides
Paek, Seung Hwan,Shim, Sang Chul,Cho, Chan Sik,Kim, Tae-Jeong
, p. 849 - 851 (2007/10/03)
1,2-Ferrocenediylazaphosphinines (1a-c) have been successfully employed as a new class of nucleophilic catalysts for ring-opening of a range of epoxides, their catalytic efficiency in terms of regioselectivity as well as chemical yield comparing well with the existing catalysts in the literature. In contrast, low enantiomeric excesses have been obtained from the reactions of meso-epoxides catalyzed by (R)-1.
