10309-65-6 Usage
Description
[1S-(1alpha,3beta,4alpha,6alpha)]-3-hydroxy-3,7,7-trimethylbicyclo[4.1.0]hept-4-yl acetate is a bicyclic compound characterized by its unique molecular structure, which includes a bicyclo[4.1.0]heptane ring system with three methyl groups and a hydroxyl group positioned at specific locations within the ring. [1S-(1alpha,3beta,4alpha,6alpha)]-3-hydroxy-3,7,7-trimethylbicyclo[4.1.0]hept-4-yl acetate also features an ester linkage formed by the attachment of an acetate group to the hydroxyl group. This distinctive structure and composition make it a promising candidate for various applications in organic synthesis and pharmaceutical research, as well as in the development of new chemical compounds and materials.
Uses
Used in Organic Synthesis:
[1S-(1alpha,3beta,4alpha,6alpha)]-3-hydroxy-3,7,7-trimethylbicyclo[4.1.0]hept-4-yl acetate is used as a key intermediate in the synthesis of complex organic molecules. Its unique structure and functional groups allow for a wide range of chemical reactions, making it a valuable building block for the creation of novel compounds with diverse applications.
Used in Pharmaceutical Research:
In the pharmaceutical industry, [1S-(1alpha,3beta,4alpha,6alpha)]-3-hydroxy-3,7,7-trimethylbicyclo[4.1.0]hept-4-yl acetate is used as a starting material for the development of new drugs. Its specific structure and properties can be exploited to design and synthesize bioactive molecules with potential therapeutic applications, such as those targeting various diseases and medical conditions.
Used in Material Science:
[1S-(1alpha,3beta,4alpha,6alpha)]-3-hydroxy-3,7,7-trimethylbicyclo[4.1.0]hept-4-yl acetate can be utilized in the development of new materials with unique properties. Its molecular structure and functional groups can be tailored to create materials with specific characteristics, such as improved mechanical strength, thermal stability, or chemical resistance, depending on the desired application.
Check Digit Verification of cas no
The CAS Registry Mumber 10309-65-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,3,0 and 9 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 10309-65:
(7*1)+(6*0)+(5*3)+(4*0)+(3*9)+(2*6)+(1*5)=66
66 % 10 = 6
So 10309-65-6 is a valid CAS Registry Number.
10309-65-6Relevant articles and documents
THE ALDOL-TYPE CONDENSATION OF LITHIUM, BORON AND TITANIUM ENOLATES OF ISOCARANYL ACETATES WITH BENZALDEHYDE. THE METAL AND CHIRAL AUXILIARY EFFECTS
Fringuelli, Francesco,Piermatti, Oriana,Pizzo, Ferdinando,Scappini, Anna Maria
, p. 195 - 200 (2007/10/02)
A new approach to chiral enolates by using a chiral ester (isocaranyl acetates) and a chiral organometallic reagent (boranes and titanates) is reported.The effect of this double enantiodifferentiation and the effects of the isomerism of chiral auxiliary (2- and 4-isocaranyl) and that of the metal (Li, B, Ti) on the enantioselectivity of aldol condensation of 2- and 4-isocaranyl acetates with benzaldehyde are discussed.Lithium and boron enolates of isocaranyl acetates add preferentially to the si-face of benzaldehyde while the addition of analogous titanium enolates occurs preferably on the re-face of the aldehyde.The enolborinate which gives the highest ee value is that obtained by transmetallation reaction of the lithium enolate of (+)-2-isocaranyl acetate with (-)-di-4-isocaranylchloroborane.Obversely the enoltitanate prepared from (-)-4-isocaranyl acetate and the LDA-(+)-di-2-isocaranoxy(chloro)cyclopentadienyl titanate system is that which gives the highest enantiofacial discrimination.The chiral auxiliary effect has been used to plan the synthesis of (+)-4α-acetoxy-3β-trimethylsilyloxy-trans-carane, the titanium enolate of which gives (R)-(+)-β-hydroxy-β-phenylpropionic acid in high enantiomeric excess.