103162-61-4

Basic information

• Product Name: Phenanthrene, 9,10-bis(4-methoxyphenyl)-
• CAS NO: 103162-61-4
• Molecular Formula: C28H22O2
• Molecular Weight: 390.481
• Mol File: 103162-61-4.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Phenanthrene, 9,10-bis(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenanthrene, 9,10-bis(4-methoxyphenyl)-(103162-61-4)
• EPA Substance Registry System: Phenanthrene, 9,10-bis(4-methoxyphenyl)-(103162-61-4)

Safety Data

• Hazardous Substances Data: 103162-61-4(Hazardous Substances Data)

Upstream product

• 861004-01-5 (+/-)-10-Hydroxy-9,9-bis-(4-methoxy-phenyl)-9,10-dihydro-phenanthren 
• 20837-34-7 2,2'-bis(4-methoxybenzoyl)biphenyl 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 105930-73-2 (4-Methoxy-phenyl)-[2'-(4-methoxy-thiobenzoyl)-biphenyl-2-yl]-methanone 
• 124120-74-7 phenanthrene-9,10-dione-mono-benzhydrylidenehydrazone 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 123-11-5 4-methoxy-benzaldehyde 
• 2871-87-6 p-methoxybenzylidene fluorene 
• 100-66-3 methoxybenzene 
• 768-60-5 4-methoxyphenylacetylen 
• 3989-14-8 (4-methoxyphenylethynyl)trimethylsilane 
• 696-62-8 para-iodoanisole 
• 591-50-4 iodobenzene 
• 2132-62-9 4,4'-dimethoxydiphenylacetylene 

Relevant articles and documents

Synthesis of diarylated aromatic hydrocarbons by dehydroxylation of diols using the titanium(IV) chloride and triethylamine reagent system

1,2-Diarylacenaphthylene, 9,10-diarylphenanthrene and 9,10-diarylanthracene derivatives were obtained in good yields (61-92%) in short reaction times (5-30 min) from the corresponding diols with the titanium(III) reagent prepared in situ using the TiCl4/Et3N reagent system in dichloromethane at 25 °C. Georg Thieme Verlag Stuttgart ? New York.

Intermolecular oxidative Friedel-Crafts reaction triggered ring expansion affording 9,10-diarylphenanthrenes

A novel intermolecular tandem oxidative aromatic coupling between arylidene fluorenes and unfunctionalized aromatics mediated by a DDQ/TFA oxidation system has been developed for the construction of 9,10-diary-lphenanthrenes (DAPs). The formation of a benzylic carbocation species possessing a quaternary sp3-carbon center on the fluorene moiety by an intermolecular oxidative Friedel-Crafts reaction of two different arenes successfully triggered the subsequent ring expansion to afford DAPs.

Synthetic method of phenanthrene, and phenanthrene derivative

The invention discloses a synthetic method of phenanthrene, and a phenanthrene derivative. The synthetic method comprises following steps: under nitrogen gas protection, in a toluene solution, an o-bromoiodobenzene compound, aryl boric acid, and a diaryl