10319-01-4Relevant articles and documents
Oxovanadium(V) complexes with schiff base Ligands: Synthesis, Structure, and catalytic property
Wang, Ning,Guo, Jing-Yi,Hu, Ji-Yong
, p. 125 - 129 (2014)
The reaction of [VO(acac)2] with N,N-ethylenebis(3-ethoxysalicylideneimine) (H2L1) and N,N-ethylenebis(3-methylsalicylideneimine) (H2L2), respectively, in methanol, affords two new oxovanadium(V) complexes, [VOL1]H2O (1) and [VOL2] (2). Both complexes hav
Syntheses of the Carotane-type Terpenoids (+)-Schisanwilsonene A and (+)-Tormesol via a Two-Stage Approach
Chen, Kai-Yue,Mou, Shu-Bin,Wang, Hua-Qi,Xiang, Zheng,Xiao, Wen
supporting information, p. 400 - 404 (2021/01/13)
Stereoselective syntheses of terpenoids in a more efficient manner have been a long-term pursuit for synthetic chemists. Herein we describe the two-step, enantiospecific and protecting-group-free synthesis of (+)-schisanwilsonene A from a carotane compound, which was produced in E. coli. We also completed the first enantiomeric synthesis of (+)-tormesol in five steps. The two-stage strategy offers a step- and redox-economical approach to prepare terpene natural products and their analogues.