103224-64-2

Basic information

• Product Name: Ethanone, 1-[2,3,4,5-tetramethyl-6-(nitromethyl)phenyl]-
• CAS NO: 103224-64-2
• Molecular Formula: C13H17NO3
• Molecular Weight: 235.283
• Mol File: 103224-64-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[2,3,4,5-tetramethyl-6-(nitromethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[2,3,4,5-tetramethyl-6-(nitromethyl)phenyl]-(103224-64-2)
• EPA Substance Registry System: Ethanone, 1-[2,3,4,5-tetramethyl-6-(nitromethyl)phenyl]-(103224-64-2)

Safety Data

• Hazardous Substances Data: 103224-64-2(Hazardous Substances Data)

Usage

General Description

"Ethanone, 1-[2,3,4,5-tetramethyl-6-(nitromethyl)phenyl]-" is a chemical compound with a complex molecular structure that includes a ketone group attached to a phenyl ring. The phenyl ring is substituted with four methyl groups and a nitromethyl group at positions 2, 3, 4, 5, and 6. Ethanone, 1-[2,3,4,5-tetramethyl-6-(nitromethyl)phenyl]- is likely to have diverse chemical and physical properties due to the presence of both electron-donating and electron-withdrawing substituents on the phenyl ring. Further research may be needed to determine the specific uses, applications, and potential hazards of this compound.

Upstream product

• 2040-01-9 2',3',4',5',6'-pentamethylacetophenone 
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Relevant articles and documents

Positional Reactivity of Acylpolymethylbenzenes in Electrophilic Substitution

Friedel-Crafts acylation, bromination, deuteration, and nitration of acetylpentamethylbenzene (APMB), 1-acetyl-2,3,4,6-tetramethylbenzene (ATMB), and 1-benzoyl-2,3,4,6-tetramethylbenzene (BTMB) and the resulting product distribution were investigated.Friedel-Crafts acylation, bromination, and deuteration of APMB and Friedel-Crafts acylation of ATMB gave deacetylation-substitution products.On the other hand, bromination and deuteration of ATMB (or BTMB) and Friedel-Crafts acylation of BTMB gave 5-substituted products.In both cases, the positional reactivities were in accordance with the relative ?-complex stability.Conversely, except for Friedel-Crafts-type nitration, the positional reactivities in the nitration of these substrates were strikingly different from those of the above three reactions.Thus, side-chain functionalization at the 6-methyl group occurred in nitration with fuming nitric acid, depending on the solvents in use.The NMDO calculations and the reaction of APMB with single-electron transfer reagents such as tetranitromethane-hν or cerium(IV) ammonium nitrate suggest that the product distribution in nitration can be explained in terms of a single-electron transfer mechanism.