1033321-92-4

Basic information

• Product Name: C₂₁H₃₁N₃
• Synonyms: C₂₁H₃₁N₃
• CAS NO: 1033321-92-4
• Molecular Weight: 325.497
• Mol File: 1033321-92-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₁H₃₁N₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₁H₃₁N₃(1033321-92-4)
• EPA Substance Registry System: C₂₁H₃₁N₃(1033321-92-4)

Safety Data

• Hazardous Substances Data: 1033321-92-4(Hazardous Substances Data)

Upstream product

• 496-15-1 1-indoline 
• 29882-02-8 N',N''-dicyclohexyl-N,N-dimethylguanidine 

Relevant articles and documents

Titanacarborane mediated C-N bond forming/breaking reactions

Constrained-geometry titanacarboranes [σ:η1:η5-(OCH2)(R2NCH2)C2B9H9]Ti(NR2) (R = Me, Et) are synthesized via an unexpected reaction of [Me3NH][μ-7,8-CH2OCH2-7,8-C2B9H10] with Ti(NR2)4 (R = Me, Et), involving a C-O bond cleavage and C-N bond formation. These complexes can be readily converted to new amide species or alkoxide by reacting with amines or esters, respectively. Insertion of a series of unsaturated molecules into the Ti-N bond of the aforementioned complexes results in the formation of various half-sandwich titanacarboranes. [σ:η1:η5-(OCH2)(Me2NCH2)C2B9H9]Ti(NMe2) is also able to efficiently catalyze the hydroamination of carbodiimides and the transamination of guanidines. These results are summarized in this brief account.