103360-21-0Relevant articles and documents
Allylation and cyanation of aza-aromatics activated by chloroformate and a catalytic amount of iodine
Yadav,Reddy,Srinivas,Sathaiah
, p. 3489 - 3492 (2005)
Allyltrimethylsilane and trimethylsilyl cyanide undergo smooth addition to N-acylated quinolines in the presence of a catalytic amount of iodine to afford 2-allyl- and 2-cyano-1,2-dihydroquinoline derivatives, respectively in good yields with high chemo- and regioselectivity. A variety of functional groups such as alkyl, alkoxy, halo, and nitro functionalities are tolerated under the reaction conditions.
REISSERT COMPOUND STUDIES LXIII: PREPARATION OF REISSERT COMPOUNDS USING DIETHYLALUMINIUM CYANIDE
Duarte, Frederick F.,Popp, Frank D.
, p. 723 - 726 (2007/10/02)
Reissert compounds and analogs were synthesized from the reaction of acid halide, heterocyclic base and diethylaluminium cyanide.This new method of Reissert compound synthesis gave yields comparable to other synthetic routes.
THE USE OF 18-CROWN-6 AS PHASE TRANSFER CATALYST IN THE REISSERT REACTION
Chenevert, Robert,Lemieux, Even,Voyer, Normand
, p. 1095 - 1102 (2007/10/02)
Solid-liquid phase transfer of cyanide ion by 18-crown-6 increases the yield of the Reissert reaction and eliminates the undesirable pseudo-base formation.
