103533-58-0

Basic information

• Product Name: [Rh(5,10,15,20-tetraphenylporphyrinato)(ethyl)]
• Synonyms: [Rh(5,10,15,20-tetraphenylporphyrinato)(ethyl)]
• CAS NO: 103533-58-0
• Molecular Weight: 744.7
• Mol File: 103533-58-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Rh(5,10,15,20-tetraphenylporphyrinato)(ethyl)](CAS DataBase Reference)
• NIST Chemistry Reference: [Rh(5,10,15,20-tetraphenylporphyrinato)(ethyl)](103533-58-0)
• EPA Substance Registry System: [Rh(5,10,15,20-tetraphenylporphyrinato)(ethyl)](103533-58-0)

Safety Data

• Hazardous Substances Data: 103533-58-0(Hazardous Substances Data)

Upstream product

• 69509-35-9 RhI(tetraphenylporphyrin) 
• 634-35-5 N-ethylquinolinium iodide 
• 26670-42-8 1-ethylquinolin-1-ium bromide 
• 71-91-0 tetraethylammonium bromide 
• 77-98-5 tetraethylammonium hydroxide 

Relevant articles and documents

Alkylation of rhodium porphyrins using ammonium and quinolinium salts

Alkylation of rhodium(III) porphyrins [RhIII(por)] was achieved under relatively mild conditions in up to 98% yields, where readily available ammonium and quinolinium salts were utilized as the alkylating agents. This transformation tolerates air and water, thus serving as a convenient method to prepare a variety of alkyl- and benzyl-RhIII(por) complexes. Preliminary mechanistic studies support an SN2-like reaction pathway involving a RhI(por) anion intermediate.