1035818-07-5

Basic information

• Product Name: N,N’-bis[2-carboxybenzomethyl]-N,N’-bis[carboxymethyl]-1,3-diaminopropan-2-ol dihydrochloride
• Synonyms: N,N’-bis[2-carboxybenzomethyl]-N,N’-bis[carboxymethyl]-1,3-diaminopropan-2-ol dihydrochloride
• CAS NO: 1035818-07-5
• Molecular Weight: 474.467
• Mol File: 1035818-07-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N,N’-bis[2-carboxybenzomethyl]-N,N’-bis[carboxymethyl]-1,3-diaminopropan-2-ol dihydrochloride(CAS DataBase Reference)
• NIST Chemistry Reference: N,N’-bis[2-carboxybenzomethyl]-N,N’-bis[carboxymethyl]-1,3-diaminopropan-2-ol dihydrochloride(1035818-07-5)
• EPA Substance Registry System: N,N’-bis[2-carboxybenzomethyl]-N,N’-bis[carboxymethyl]-1,3-diaminopropan-2-ol dihydrochloride(1035818-07-5)

Safety Data

• Hazardous Substances Data: 1035818-07-5(Hazardous Substances Data)

Upstream product

• 1035568-97-8 N,N'-bis[2-carboxybenzomethyl]-N,N'-bis[2-pyridylmethyl]-1,3-diaminopropan-2-ol 
• 79-08-3 bromoacetic acid 
• 64-69-7 Iodoacetic acid 
• 119-67-5 o-carboxybenzaldehyde 

Relevant articles and documents

Synthesis, crystal structure, magnetic and electrochemical studies of two copper complexes with carboxylate rich dinucleating ligand

Three new copper compounds of a symmetric dinucleating ligand, N,N′-bis[2-carboxybenzomethyl]-N,N′-bis[carboxymethyl]-1, 3-diaminopropan-2-ol (H5ccdp) with diverse coordinating groups, have been synthesized and studied in the solid state as well as in solution. In acetonitrile/H2O solution, the reaction of stoichiometric amounts of Cu(NO3)2·2.5H2O and the ligand H 5ccdp, in the presence of K2CO3, produced a dinuclear copper compound, K3[Cu2(ccdp)(μ-CO 3)]·7H2O·C3H6O, K 3[1]·7H2O·C3H6O. Whereas in an alkaline methanol/water solution, the reaction of Cu(ClO 4)2·6H2O and the ligand H 5ccdp gave a slightly different dinuclear copper compound, Na 3[Cu2(ccdp)(μ-CO3)]·5H2O, Na3[1]·5H2O. The reaction of Cu(ClO 4)2·6H2O and the ligand H 5ccdp, in the presence of NaOH in water yielded a tetranuclear copper compound, Na2[Cu2(ccdp)(H2O)(μ-OH 2)]2·15H2O, Na2[2] ·15H2O. The structures of the all three complexes were determined using single crystal X-ray diffraction analyses. Variable-temperature magnetic susceptibility studies on the powder samples of the complexes showed antiferromagnetic behavior. Electrochemical studies in aqueous solutions of these negatively charged complex ions showed fairly assessable oxidations.

Crystal structure of gluconate bound iron(iii) complex: Synthesis, characterization and redox properties of the complex in aqueous solution

A novel tetra-iron(iii) complex, K6[Fe4(ccdp)2(μ-O)(μ-OH)(D-GluA)2](NO3)3·10H2O (K6[1](NO3)3·10H2O) with two gluconato and two N,N′-bis[2-carboxobenzomethyl]-N,N′-bis[carboxomethyl]-1,3-diaminopropan-2-oxy (ccdp5-) ligands has been synthesized and fully characterized using different techniques including single crystal X-ray crystallography. K6[1](NO3)3·10H2O showed stability aqueous solution, in biological samples such as human and fetal bovine serum (HS and FBS) and cell cultures such as phosphate buffer saline and minimum essential medium (PBS and MEM) using UV-Vis spectroscopy at room temperature and 37 °C. The redox behavior of the complex was studied using cyclic and square wave voltammetries in aqueous and DMF solutions. Furthermore, magnetic study using electron paramagnetic resonance spectroscopy and Guoy balance magnetic moment measurements indicated antiferromagnetic coupling among the metal centers of the (μ-O)(μ-OH) bridged tetra-iron(iii) anion core of the complex. Electrochemical studies of the K6[1](NO3)3·10H2O in aqueous and DMF solutions using cyclic and square-wave voltammetries revealed the presence of multi-accessible electron metal-based redox events.