103655-02-3Relevant articles and documents
Direct electroreduction or use of an electrogenerated base : Two ways for the coupling of polyhalogenated compounds with aldehydes or ketones
Barhdadi, Rachid,Simsen, Blandine,Troupel, Michel,Nedelec, Jean-Yves
, p. 1721 - 1728 (2007/10/03)
The electrochemical coupling of polyhalogenated compounds with carbonyl compounds is achieved in two ways. A carbanion RX(n)- is generated either by the direct electroreduction of RX(n)Cl or by deprotonation of RX(n)H. In this latter case the base Ph- is electrogenerated by reduction of iodobenzene. All electrolysis were carried out in an undivided cell fitted with a cadmium-coated cathode and an aluminium or magnesium sacrificial anode.
PbBr2/Al-Promoted Reductive Addition of 1,1,1-trichloro-2,2,2-trifluoroethane (Flon) to Aldehydes
Tanaka, Hideo,Yamashita, Shiro,Katayama, Yasumi,Torii, Sigeru
, p. 2043 - 2044 (2007/10/02)
Introduction of CF3CCl2 unit into aldehydes with CF3CCl3 has been perfomed successfully by the action of catalytic PbBr2 and Al foils in DMF.