103659-46-7

Basic information

• Product Name: 2-Cyclohexene-1-methanol, 2-methyl-a-(trichloromethyl)-
• CAS NO: 103659-46-7
• Molecular Formula: C9H13Cl3O
• Molecular Weight: 243.561
• Mol File: 103659-46-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexene-1-methanol, 2-methyl-a-(trichloromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexene-1-methanol, 2-methyl-a-(trichloromethyl)-(103659-46-7)
• EPA Substance Registry System: 2-Cyclohexene-1-methanol, 2-methyl-a-(trichloromethyl)-(103659-46-7)

Safety Data

• Hazardous Substances Data: 103659-46-7(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 590-67-0 1-Methylcyclohexanol 
• 75-87-6 chloral 

Downstream Products

• 15564-32-6 1-(2-methyl-cyclohex-2-enyl)-ethanone 
• 103659-58-1 (Z)-6-(2-chlorovinyl)-1-methylcyclohexene 

Relevant articles and documents

Lewis Acid Catalysis of Ene Addition of Chloral and Bromal to Olefins; Product Studies

The addition of chloral and bromal to a variety of alkyl-substituted alkenes has been investigated.The effect of the reaction of varying the Lewis acid catalyst and the structure of substrate have been studied.Anhydrous AlCl3 was found to be most effective catalyst, and ene-type adducts were the major products in most cases.Side reactions were observed with the less reactive systems leading, variously, to the formation of trihalogenoketones, hydrohalogenated ene adducts, and cyclic ethers.Conditions for optimising the yield of ene adducts were established in some cases.The trihalogenoketone by-products can be conveniently removed by a Grignard-type reaction.