10374-66-0

Basic information

• Product Name: Butanethioamide, 3-oxo-N-phenyl-
• CAS NO: 10374-66-0
• Molecular Formula: C10H11NOS
• Molecular Weight: 193.269
• Mol File: 10374-66-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Butanethioamide, 3-oxo-N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Butanethioamide, 3-oxo-N-phenyl-(10374-66-0)
• EPA Substance Registry System: Butanethioamide, 3-oxo-N-phenyl-(10374-66-0)

Safety Data

• Hazardous Substances Data: 10374-66-0(Hazardous Substances Data)

Upstream product

• 13588-39-1 2-acetyl-3-oxo-N-phenylbutanethioamide 
• 102-01-2 N-phenylacetoacetamide 
• 59846-87-6 3-(N-Phenylamino-thiocarbonyl)-4-amino-3-penten-2-one 
• 73028-16-7 3-chloro-5-methyl-2-phenylisoxazolium chloride 
• 103-72-0 phenyl isothiocyanate 
• 123-54-6 acetylacetone 

Downstream Products

• 21334-93-0 4,5-dimethyl-2-(2-oxo-propyl)-3-phenyl-thiazolium; bromide 
• 847453-92-3 3-(3-methyl-5-phenylamino-pyrazol-1-yl)-propionitrile 
• 501325-80-0 acetothioacetanilide benzoylhydrazone 
• 324000-16-0 2-anilino-2-ethoxy-3-oxothiobutanoic acid anilide 
• 28813-70-9 1,1'-(4-phenyl-[1,2,4]dithiazolidine-3,5-diylidene)-bis-propan-2-one 
• 18071-08-4 1-(5-anilino-[1,2,3]thiadiazol-4-yl)-ethanone 
• 60728-82-7 5-methyl-3-(2-oxo-propylidene)-4-phenyl-3,4-dihydro-[1,2,4]dithiazepin-7-one 
• 10394-28-2 N-Phenyl-N'-o-tolyl-dithiomalonsaeure-diamid 

Relevant articles and documents

Sulfur-Containing Heterocycles Derived by Reaction of ω-Keto Amides with Lawesson's Reagent

The reaction of ω-keto amides with Lawesson's reagent (LR: 2,4-bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide) is described. Treatment of 3-keto amides (2-acylacetamides) 1 with LR gave the corresponding 3-keto thioamides 2, along with 1,2-dithiole-3-thiones 3. Treatment of 4-keto amides, 3-acyl propionamides 5, with LR yielded five-membered heterocycles, pyrroles 6 and/or 2-aminothiophenes 7. 5-Keto amides, 3-benzoyl butyramides 8, reacted with LR to give dihydrothiopyran-2-thione 9 as the sole product, but in low yield. 2-Acylbenzamides 10 also reacted with LR to afford 3-mercaptoisoindolin-2-ones 11 or dihydroisobenzothiophene-1-thiones 12.

Reactivity of α-acylated β-enamino ketones and esters: Synthesis of pyrazoles

The reactivity of the enamino compounds 4-amino-3-phenylamino(thio)carbonyl-3-penten-2-one 1 and 2 and ethyl 3-amino-2-phenylamino(thio)carbonyl-2-butyrate 7 and 8 was studied using the reaction with hydrazine hydrate and hydrazine hydrochloride to evaluate the 1,3 electrophilic center of the compounds by the formation of the pyrazole rings. The pyrazoles 3,4,5,9,11 and 13 were obtained depending on the reaction conditions employed.

Novel crotonanilides

Novel crotonanilides of the formula STR1 wherein Z is selected from the group consisting of --O-- and --S--, R is selected from the group consisting of alkyl of 1 to 6 carbon atoms and optionally substituted phenyl, X and Y are individually selected from the group consisting of hydrogen, halogen, lower alkyl of 1 to 6 carbon atoms optionally substituted with at least one halogen, alkoxy of 1 to 3 carbon atoms, alkylthio and alkylsulfinyl of 1 to 6 carbon atoms, acyl of an organic carboxylic acid of 1 to 6 carbon atoms, --NO2 and --CF3, R1 is selected from the group consisting of hydrogen, chlorine, bromine, alkoxycarbonyl with 1 to 6 alkyl carbon atoms, nitro and alkylthio, alkylsulfinyl and alkylsulfonyl of 1 to 3 alkyl carbon atoms and R2 is alkyl of 1 to 6 carbon atoms, said compounds existing in the form of their E or Z isomers or mixtures thereof and having herbicidal properties.