10375-18-5

Basic information

• Product Name: Boranediamine, N,N'-bis(1,1-dimethylethyl)-1-phenyl-
• CAS NO: 10375-18-5
• Molecular Formula: C14H25BN2
• Molecular Weight: 232.177
• Mol File: 10375-18-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Boranediamine, N,N'-bis(1,1-dimethylethyl)-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Boranediamine, N,N'-bis(1,1-dimethylethyl)-1-phenyl-(10375-18-5)
• EPA Substance Registry System: Boranediamine, N,N'-bis(1,1-dimethylethyl)-1-phenyl-(10375-18-5)

Safety Data

• Hazardous Substances Data: 10375-18-5(Hazardous Substances Data)

Upstream product

• 873-51-8 phenylborondichloride 
• 37828-54-9 lithium tert-butylamide 
• 37480-53-8 2-phenyl-1,3,2-diazaboracyclopentane 
• 13070-19-4 2-phenyl-[1,3,2]diazaborinane 
• 960-71-4 triphenylborane 
• 71-43-2 benzene 
• 3262-89-3 triphenylboroxine 
• 591-50-4 iodobenzene 
• 100-56-1 phenylmercury(II) chloride 
• 100123-15-7 chloro-phenoxy-phenyl-borane 
• 75-64-9 tert-butylamine 

Downstream Products

• 96931-78-1 C₆H₅B{NC₆H₅CONH-t-C₄H₉}2 
• 40218-41-5 bis(phenylamino) phenylborane 
• 118331-74-1 (t-butylimino)phenylborane 
• 75-64-9 tert-butylamine 
• 72886-52-3 1,3,5-tri-t-butyl-2,4,6-triphenylborazine 
• 124652-56-8 bis(tert-butylamino)phenylborane dilithium salt 
• 124652-54-6 1,3-di-tert-butyl-4,4-dimethyl-1,3-diaza-2-stanna-4-boracyclobutane 
• 102159-65-9 C₆H₅B(NHC₆H₄-4-CH₃)2 
• 124685-97-8 1,3-di-tert-butyl-4,4-bis(cyclopentadienyl)-2-phenyl-1,3-diaza-2-bora-4-zirconia-cyclobutane 
• 478000-97-4 Li2[PhB(μ3-N(t)Bu)2] 
• 124652-52-4 4,4'-spirobis{1,3-di(tert-butyl)-2-phenyl-1,3-diaza-2-bora-4-titaniacyclobutane} 
• 124652-51-3 4,4'-spirobis{1,3-di(tert-butyl)-2-phenyl-1,3-diaza-2-bora-4-tinacyclobutane} 
• 124652-50-2 4,4'-spirobis{1,3-di(tert-butyl)-2-phenyl-1,3-diaza-2-bora-4-germaniacyclobutane} 
• 16672-48-3 hexaphenylborazine 

Relevant articles and documents

Syntheses and X-ray structures of boraamidinate complexes of lithium, phosphorus, and tellurium

The dilithiated boraamidinate complexes {Li2[RB(N-t-Bu)2]}2 (1a, R = Ph; 1b, R = t-Bu), prepared by the reaction of B[N(H)-t-Bu]3 with three equivalents of LiR, are shown by X-ray crystallography to have dimeric structures consisting of a distorted Li4N4 cube capped on two opposite faces by RB units. Reactions of 1a with TeCl4 or PX3 (X = Cl, Br) yielded complexes PhB(μ-N-t-Bu)2TeCl2 (2) and PhB(μ-N-t-Bu)2PX (4a, X = Cl; 4b, X = Br), respectively. The structures of 2 and 4b were determined by X-ray crystallography. In the solid state, complex 2 forms a dimer with weak Te···Cl contacts (3.2411(6) A). Complex 4b is monomeric with a P-Br bond length of 2.3047(11) A. The reactions of 2 and 4a with the appropriate amounts of Li[N(H)-t-Bu] produce the monomeric tellurium imide PhB(μ-N-t-Bu)2Te=N-t-Bu and the amido derivative PhB(μ-N-t-Bu)2PN(H)-t-Bu (4c), respectively. The X-ray structure of 4c was determined. Deprotonation of 4c with n-BuLi produces the dimeric monolithium derivative {Li[PhB(μ-N-t-Bu)2PN-t-Bu]}2 (5), which was shown by X-ray crystallography to have a centrosymmetric structure with a central transoid Li2N2 ring.