10375-46-9Relevant articles and documents
Highly efficient addition of activated methylene compounds to alkenes catalyzed by gold and silver
Yao, Xiaoquan,Li, Chao-Jun
, p. 6884 - 6885 (2004)
A highly efficient intermolecular addition of 1,3-diketones to alkenes catalyzed by AuCl3/AgOTf was developed. A mechanistic rationale for the reaction has been proposed via a α-C-H activation. Copyright
Solvent-free alkylation of 1,3-dicarbonyl compounds with benzylic, propargylic and allylic alcohols catalyzed by La(NO3)3·6H2O
Subramanyam, Madala,Rao, Koya Prabhakara,Varala, Ravi,Rao, Mandava V. Basaveswara
, p. 1155 - 1160 (2016/03/01)
An efficient and solvent free method for benzylation, propargylation and allylation of 1,3-dicarbonyl compounds with alcohols has been developed by using La(NO3)3·6H2O as water tolerable catalyst. The reaction was shown to proceed smoothly for various 1,3-dicarbonyl compounds with benzylic, propargylic and allylic alcohols including 1° allylic alcohols, without any solvent, providing a clean access to the desired products in short reaction times with good to excellent yields and high selectivity.
Heteropoly acid-catalyzed highly efficient alkylation of 1,3-dicarbonyl compounds with benzylic and propargylic alcohols
Yadav,Subba Reddy,Pandurangam,Raghavendra Rao,Praneeth,Narayana Kumar,Madavi,Kunwar
, p. 4296 - 4301 (2008/09/21)
Various 1,3-dicarbonyl compounds reacted readily with benzylic and propargylic alcohols in the presence of 10 mol % of phosphomolybdic acid supported on silica gel (PMA/SiO2) under mild reaction conditions to produce 2-benzylic- and 2-propargyl
