103883-30-3

Basic information

• Product Name: [(4S)-2,2-Dimethyl-1,3-dioxolan-4-yl]methanamine
• Synonyms: 2,2-DIMETHYL-4(R)-4-AMINOMETHYL-1,3-DIOXALANE;2,2-DIMETHYL-4(S)-4-AMINOMETHYL-1,3-DIOXALANE;1,3-DIOXOLANE-4-METHANAMINE, 2,2-DIMETHYL-, (R);1,3-DIOXOLANE-4-METHANAMINE, 2,2-DIMETHYL-, (S);(R)-(-)-(2,2-DIMETHYL-[1,3]-DIOXOLAN-4-YL)-METHYLAMINE;(R)-4-AMINOMETHYL-2,2-DIMETHYL-1,3-DIOXOLANE;(S)-3-AMINO-1,2-DIHYDROXYPROPANE ISOPROPYLIDENE ACETAL;(S)-4-AMINOMETHYL-2,2-DIMETHYL-1,3-DIOXOLANE
• CAS NO: 103883-30-3
• Molecular Formula: C₆H₁₃NO₂
• Molecular Weight: 131.17
• Mol File: 103883-30-3.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 168.847°C at 760 mmHg
• Flash Point: 57.552°C
• Appearance: /
• Density: 0.979g/cm³
• Vapor Pressure: 1.587mmHg at 25°C
• Refractive Index: 1.43
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• PKA: 9.16±0.29(Predicted)
• CAS DataBase Reference: [(4S)-2,2-Dimethyl-1,3-dioxolan-4-yl]methanamine(CAS DataBase Reference)
• NIST Chemistry Reference: [(4S)-2,2-Dimethyl-1,3-dioxolan-4-yl]methanamine(103883-30-3)
• EPA Substance Registry System: [(4S)-2,2-Dimethyl-1,3-dioxolan-4-yl]methanamine(103883-30-3)

Safety Data

• Hazard Codes: Xn
• Statements: 22-41-43
• Safety Statements: 26-36/37/39
• RIDADR: 1760
• HazardClass: 8
• PackingGroup: Ⅲ
• Hazardous Substances Data: 103883-30-3(Hazardous Substances Data)

Usage

General Description

"[(4S)-2,2-Dimethyl-1,3-dioxolan-4-yl]methanamine" is a chemical compound that belongs to the group of Organic compounds known as acetals. Being a chiral compound, it has a specific spatial arrangement of atoms, with a form known as the 4S stereoisomer. It consists of a 1,3-dioxolane ring, which is a type of acetal, a functional group that includes two alkoxy groups bonded to the same carbon. Additionally, this chemical also has an amino (-NH2) group attached, along with two methyl (CH3) branches. This means it has both basic and ether-like properties. The exact application of this substance may vary, it is not normally found in a natural environment but it's generally used in scientific research or possibly in the synthesis of other compounds in the pharmaceutical or chemical manufacturing industries.

InChI:InChI=1/C6H13NO2/c1-6(2)8-4-5(3-7)9-6/h5H,3-4,7H2,1-2H3/t5-/m1/s1

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Relevant articles and documents

Stereochemistry-Controlled Supramolecular Architectures of New Tetrahydroxy-Functionalised Amphiphilic Carbocyanine Dyes

The syntheses of novel amphiphilic 5,5′,6,6′-tetrachlorobenzimidacarbocyanine (TBC) dye derivatives with aminopropanediol head groups, which only differ in stereochemistry (chiral enantiomers, meso form and conformer), are reported. For the achiral meso form, a new synthetic route towards asymmetric cyanine dyes was established. All compounds form J aggregates in water, the optical properties of which were characterised by means of spectroscopic methods. The supramolecular structure of the aggregates is investigated by means of cryo-transmission electron microscopy, cryo-electron tomography and AFM, revealing extended sheet-like aggregates for chiral enantiomers and nanotubes for the mesomer, respectively, whereas the conformer forms predominately needle-like crystals. The experiments demonstrate that the aggregation behaviour of compounds can be controlled solely by head group stereochemistry, which in the case of enantiomers enables the formation of extended hydrogen-bond chains by the hydroxyl functionalities. In case of the achiral meso form, however, such chains turned out to be sterically excluded.