104089-46-5

Basic information

• Product Name: P(C₆H₅)4⁽¹⁺⁾*Mo(CH₃N(H)CS₂)(CO)4^(1-)=P(C₆H₅)4[Mo(CH₃N(H)CS₂)(CO)4]
• CAS NO: 104089-46-5
• Molecular Weight: 653.571
• Mol File: 104089-46-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: P(C₆H₅)4⁽¹⁺⁾*Mo(CH₃N(H)CS₂)(CO)4^(1-)=P(C₆H₅)4[Mo(CH₃N(H)CS₂)(CO)4](CAS DataBase Reference)
• NIST Chemistry Reference: P(C₆H₅)4⁽¹⁺⁾*Mo(CH₃N(H)CS₂)(CO)4^(1-)=P(C₆H₅)4[Mo(CH₃N(H)CS₂)(CO)4](104089-46-5)
• EPA Substance Registry System: P(C₆H₅)4⁽¹⁺⁾*Mo(CH₃N(H)CS₂)(CO)4^(1-)=P(C₆H₅)4[Mo(CH₃N(H)CS₂)(CO)4](104089-46-5)

Safety Data

• Hazardous Substances Data: 104089-46-5(Hazardous Substances Data)

Upstream product

• 137-42-8 sodium N-methyldithiocarbamate 
• 15668-64-1 tetracarbonyl(2,2'-bipyridine)molybdenum 
• 2751-90-8 tetraphenylphosphonium bromide 
• 13939-06-5 molybdenum hexacarbonyl 

Relevant articles and documents

CARBONYL COMPLEXES OF MOLYBDENUM AND TUNGSTEN WITH SULFUR DONORS V. REACTIONS OF CARBONYL COMPLEXES OF MOLYBDENUM(0) WITH UNINEGATIVE (X,Y)-DONOR LIGANDS (X,Y = S, N, O)

The reactions of the zerovalent carbonyl complexes Mo(CO)6 and Mo(CO)4(bipy) with a series of uninegative bidentate (X,Y)-donor ligands (X,Y = xanthates, dithiocarbamates, o-aminophenoxide, o-aminothiophenoxide, 2-picolinate and thioacetate) lead to new anionic tetracarbonyl complex anions 0(X,Y)(CO)4>-.These anions, which can be isolated as their tetraphenylphosphonium salts, contain the (X,Y)-ligand as a bidentate group.In the case of (X,Y) = monothioaceate the decarbonylated species II(TA)3> is formed.The reactions of the new complexes with allyl bromide and methyl iodide are described.