104196-99-8

Basic information

• Product Name: 2-acetyl-hex-5-enoic acid ethyl ester
• CAS NO: 104196-99-8
• Molecular Weight: 184.235
• Mol File: 104196-99-8.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: 2-acetyl-hex-5-enoic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-acetyl-hex-5-enoic acid ethyl ester(104196-99-8)
• EPA Substance Registry System: 2-acetyl-hex-5-enoic acid ethyl ester(104196-99-8)

Safety Data

• Hazardous Substances Data: 104196-99-8(Hazardous Substances Data)

Upstream product

• 5162-44-7 1-bromo-4-butene 
• 141-97-9 ethyl acetoacetate 

Downstream Products

• 1414652-36-0 C₃₀H₄₂O₈ 
• 1414652-42-8 C₂₆H₃₈O₆ 
• 1370590-84-3 (1R,2S,3S)-3-[(S)-1-(tert-butyldiphenylsilanyloxy)ethyl]cyclopentane-1,2-diol` 
• 1370590-82-1 (1S,2R,3S)-3-[(S)-1-(tert-butyldiphenylsilanyloxy)ethyl]cyclopentane-1,2-diol` 
• 1370590-80-9 tert-butyl{(S)-[(S)-1-cyclopent-2-enyl]ethoxy}diphenylsilane 
• 1370590-78-5 tert-butyl[(1S,2S)-1-methyl-2-vinylhex-5-enyloxy]diphenylsilane 
• 1370590-76-3 (R)-2-[(S)-1-(tert-butyldiphenylsilanyloxy)ethyl]hex-5-enal 
• 1370590-74-1 ethyl (R)-2-[(S)-1-(tert-butyldiphenylsilanyloxy)ethyl]hex-5-enoate 
• 421765-87-9 N-Methyl-1-methyl-cis-2-hydroxymethyl-cyclopentylamin; 1t-Methylamino-1r-methyl-2t-hydroxymethyl-cyclopentan 
• 932-51-4 2,5-dimethylcyclohexanone 
• 134834-40-5 5-(but-3-enyl)-3-phenylcyclopent-2-enone 
• 139061-19-1 3-benzyloxycarbonyl-2,7-dimethyl-8-ethoxycarbonyl-1,6-dioxaspiro<4,5>deca-2,7-diene 
• 59967-05-4 hept-6-en-2-yl 4-methylbenzenesulfonate 
• 24395-10-6 6-heptene-2-ol 

Relevant articles and documents

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A general synthetic approach to para-cyclophanes via ring-closing metathesis

A new methodology for the synthesis para-cyclophanes and longithorone C frameworks has been demonstrated via alkylation, ceric ammonium nitrate (CAN) oxidation and ring-closing metathesis as key steps.

A mild Lewis acid mediated epoxy-ester to bicyclic ortho ester rearrangement

A high yielding rearrangement of epoxy-esters, under Lewis acid conditions, to give bicyclic ortho esters is reported.

New Ugi-Smiles-metathesis strategy toward the synthesis of pyrimido azepines

(Chemical Equation Presented) A new strategy involving Ugi-Smiles coupling followed by ring-closure metathesis is described herein for the preparation of pyrimidine-fused heterocyclic scaffolds. The scope of this sequence is presented in relation with the