104354-36-1

Basic information

• Product Name: Benzenemethanol, a-[1-amino-3-(methylthio)propyl]-a-phenyl-, (S)-
• CAS NO: 104354-36-1
• Molecular Formula: C17H21NOS
• Molecular Weight: 287.426
• Mol File: 104354-36-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-[1-amino-3-(methylthio)propyl]-a-phenyl-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-[1-amino-3-(methylthio)propyl]-a-phenyl-, (S)-(104354-36-1)
• EPA Substance Registry System: Benzenemethanol, a-[1-amino-3-(methylthio)propyl]-a-phenyl-, (S)-(104354-36-1)

Safety Data

• Hazardous Substances Data: 104354-36-1(Hazardous Substances Data)

Upstream product

• 63-68-3 L-methionine 
• 2899-36-7 L-methionine ethyl ester monohydrochloride 
• 100-58-3 phenylmagnesium bromide 
• 3082-77-7 L-methionine ethyl ester 
• 2491-18-1 (S)-methyl 2-amino-4-(methylthio)butanoate hydrochloride 

Downstream Products

• 1018039-48-9 (S)-2-(p-toluenesulfonylamino)-4-methylthio-1,1-diphenyl-1-butanol 
• 1018039-86-5 N-(1S)-[1-(2-methylthioethyl)-2-hydroxy-2,2-diphenyl-ethyl]-C-[(1S,4R)-7,7-dimethyl-2-oxo-bicyclo[2.2.1]hept-1-yl]-methanesulfonamide 
• 876511-09-0 (+)-4-methylsulfanyl-1.2-diphenyl-butanone-⁽¹⁾ 

Relevant articles and documents

Asymmetric reduction of prochiral ketones with N-sulfonylated amino alcohols as catalysts

Novel N-sulfonylated amino alcohols were synthesized from L-amino acids and (+)-camphor, and their application to asymmetric reduction of prochiral ketones with NaBH4-BF3·Et2O is described. Copyright Taylor & Francis Group, LLC.

Copper(II) in Organic Synthesis. XI. Evaluation of the Ligand Architecture on the Efficiency of a Copper(II) Catalyst for Enantioselective Michael Reactions.

Several bis-copper(II) complexes with chiral ligands derived from 2-substituted 2-(salicylideneamino)ethanols have been tested as catalysts of enantioselective Michael reactions.The degree of enantioselection is strongly affected by the architecture of the ligand.The best result (75percent e.e.) was obtained for a ligand having a substituent potentially suitable to induce the formation of a bis-tetradentate copper(II) complex with a square pyramidal coordination.