104354-47-4

Basic information

• Product Name: Benzene, [(1-chloropropyl)sulfinyl]-
• CAS NO: 104354-47-4
• Molecular Formula: C9H11ClOS
• Molecular Weight: 202.705
• Mol File: 104354-47-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-chloropropyl)sulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-chloropropyl)sulfinyl]-(104354-47-4)
• EPA Substance Registry System: Benzene, [(1-chloropropyl)sulfinyl]-(104354-47-4)

Safety Data

• Hazardous Substances Data: 104354-47-4(Hazardous Substances Data)

Upstream product

• 97-94-9 triethyl borane 
• 30058-54-9 α-dichloromethyl phenylsulfoxide 
• 7205-94-9 chloromethyl phenyl sulfoxide 
• 75-03-6 ethyl iodide 
• 874-79-3 phenyl(propyl)sulfide 
• 54234-79-6 propyl phenyl sulfoxide 

Downstream Products

• 145788-30-3 (E)-4-(1-Benzenesulfinyl-1-chloro-propyl)-oct-2-en-4-ol 
• 136024-48-1 (S)-(+)-3,4-epoxy-4,6-dimethyl-3-(phenylsulfinyl)octane 
• 104377-51-7 2-Benzenesulfinyl-2-chloro-1-phenyl-butan-1-ol 
• 104377-51-7 2-Benzenesulfinyl-2-chloro-1-phenyl-butan-1-ol 
• 104354-48-5 3-Benzenesulfinyl-3-chloro-nonan-4-ol 
• 104354-48-5 3-Benzenesulfinyl-3-chloro-nonan-4-ol 
• 104377-52-8 3-Benzenesulfinyl-3-chloro-2-methyl-pentan-2-ol 
• 95110-53-5 2,3-epoxy-2-methyl-3-phenylsulfinylpentane 
• 95110-51-3 1,2-epoxy-1-phenyl-2-phenylsulfinylbutane 
• 95110-51-3 1,2-epoxy-1-phenyl-2-phenylsulfinylbutane 
• 95110-50-2 3,4-epoxy-3-phenylsulfinylnonane 
• 95110-50-2 3,4-epoxy-3-phenylsulfinylnonane 
• 4170-24-5 2-chlorobutanoic acid 

Relevant articles and documents

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A Straightforward Homologation of Carbon Dioxide with Magnesium Carbenoids en Route to α-Halocarboxylic Acids

The homologation of carbon dioxide with stable, (enantiopure) magnesium carbenoids constitutes a valuable method for preparing α-halo acid derivatives. The tactic features a high level of chemocontrol, thus enabling the synthesis of variously functionalized analogues. The flexibility to generate magnesium carbenoids through sulfoxide-, halogen- or proton- Mg exchange accounts for the wide scope of the reaction. (Figure presented.).