104418-69-1Relevant articles and documents
Practical large-scale preparation of (±)-2-exo-norbornyl carboxylic acid and its improved isolation as the sodium salt
Gu, Jianxin,Storz, Thomas,Vyverberg, Frederick,Wu, Charles,Varsolona, Richard J.,Sutherland, Karen
experimental part, p. 942 - 945 (2012/07/14)
A practical, robust, and high-yielding three-step-one-pot procedure for the diastereoselective synthesis of (±)-2-exo-norbornyl carboxylic acid starting from norbornylene has been found and demonstrated on multikilogram scale, setting a new benchmark for
SILICON IN SYTHESIS-17 CHLROMETHYL(TRIMETHYLSILYL)LITHIUM-A NEW REAGENT FOR THE DIRECT CONVERSION OF ALDEHYDES AND KETONES INTO α,β-EPOXYTRIMETHYLSILANES
Burford, Clifford,Cooke, Frank,Roy, Glenn,Magnus, Philip
, p. 867 - 876 (2007/10/02)
Treatment of chloromethyltrimethylsilane 1 with sec-BuLi at -78 deg produces chloromethyl(trimethylsilyl)lithium 4.Treatment of 4 with a wide range of aldehydes and ketones gives α,β-epoxytrimethylsilanes 5-28, which on acidic hydrolysis give homologated aldehydes.