104438-58-6Relevant articles and documents
Chiral Induction in Photochemical Reactions, VI. - Asymmetric Control of the Addition of Hemipinacol Radicals to Chiral Maleates and Fumarates
Vassen, Reiner,Runsink, Jan,Scharf, Hans-Dieter
, p. 3492 - 3497 (2007/10/02)
The photocatalysed addition of 2-propanol (2) to the monoesters of maleic acid 1b and 1d yields the esters of terebic acid 5b and 5d with a diastereoselectivity up to 62percent de.The major diastereomer 5d has (2S)-configuration.Diastereoselectivity of 23