1044596-21-5Relevant articles and documents
Towards organocatalytic polyketide synthases with diverse electrophile scope: Trifluoroethyl thioesters as nucleophiles in organocatalytic Michael reactions and beyond
Alonso, Diego A.,Kitagaki, Shinji,Utsumi, Naoto,Barbas III, Carlos F.
supporting information; experimental part, p. 4588 - 4591 (2009/02/08)
(Chemical Equation Presented) Hot ester nucleophiles! Trifluoroethyl thioesters are effective nucleophiles in direct organocatalytic asymmetric Michael reactions with α,β-unsaturated aldehydes (above). Electronic tuning of thioesters allows for the genera