1046470-12-5

Basic information

• Product Name: methyl 10-cyano-dec-9-enoate
• Synonyms: methyl 10-cyano-dec-9-enoate
• CAS NO: 1046470-12-5
• Molecular Weight: 209.288
• Mol File: 1046470-12-5.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: methyl 10-cyano-dec-9-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 10-cyano-dec-9-enoate(1046470-12-5)
• EPA Substance Registry System: methyl 10-cyano-dec-9-enoate(1046470-12-5)

Safety Data

• Hazardous Substances Data: 1046470-12-5(Hazardous Substances Data)

Upstream product

• 25601-41-6 methyl 9-decenoate 
• 107-13-1 acrylonitrile 
• 2462-84-2 methyl (9E)-octadec-9-enoate 
• 13481-97-5 dimethyl (Z)-octadec-9-ene-1,18-dioate 
• 764-42-1 1,2-Dicyanoethylene 
• 20701-68-2 (9Z)-octadec-9-enedioic acid 
• 4637-24-5 N,N-dimethyl-formamide dimethyl acetal 
• 112-62-9 Methyl oleate 

Downstream Products

• 2432-99-7 11-aminoundecanoic acid 

Relevant articles and documents

Tandem catalytic acrylonitrile cross-metathesis and hydrogenation of nitriles with ruthenium catalysts: Direct access to linear α,ω- aminoesters from renewables

Fraternité, Solidarité & complémentarité en Catalyse: Tandem alkene cross-metathesis of acrylonitrile with long-chain alkene and hydrogenation catalysis is performed by using a single ruthenium-alkylidene catalyst precursor. The protocol allows the catalytic transformation of unsaturated fatty acids, derivatives of plant oils, into α,ω-aminoesters. A key step involves the reduction of nitrile-ester intermediates into aminoesters, the precursors of polyamides, with alkene metathesis catalyst residue under mild conditions. Copyright

CROSS METATHESIS PROCESS

A process for the synthesis of an unsaturated product by cross metathesis between a first unsaturated compound having at least 8 carbon atoms and a second unsaturated compound having less than 8 carbon atoms, the first unsaturated compound being capable of producing an unsaturated coproduct comprising more than 14 carbon atoms, by homometathesis, said process including at least one production phase which includes: feeding a reactor with the first unsaturated compound; feeding the reactor with the second unsaturated compound; feeding the reactor with at least a first metathesis catalysts, then feeding the reactor with at least a second metathesis catalyst; withdrawing a product stream arising from the reactor; the turnover number of the first catalyst being higher than the turnover number of the second catalyst so as to achieve the same target degree of conversion of the first unsaturated compound.

Cross-metathesis approach to produce precursors of nylon 12 and nylon 13 from microalgae

A two-step synthesis for producing methyl 12-aminododecanoate and 13-aminotridecanoate, the precursors of nylon 12 and nylon 13, from methyl oleate is described. First, methyl 11-cyano-9-undecenoate or 12-cyano-9-dodecenoate were prepared by cross metathesis of methyl oleate with either allyl cyanide or homoallyl cyanide, respectively. Subsequently, all the unsaturation of the two intermediates was hydrogenated to deliver the final products. This method represents the first synthesis of nylon 12 and 13 precursors from methyl oleate, an ester of an abundant and renewable natural fatty acid present in vegetable oil or microalgae. It also represents the shortest synthesis of nylon precursors from fatty acids, and as demonstrated in this study, can be directly applied to crude fatty acid methyl ester extracts from microalgae.