104682-98-6Relevant articles and documents
Regioselective Synthesis of 2° Amides Using Visible-Light-Induced Photoredox-Catalyzed Nonaqueous Oxidative C-N Cleavage of N, N-Dibenzylanilines
Neerathilingam, Nalladhambi,Bhargava Reddy, Mandapati,Anandhan, Ramasamy
supporting information, p. 15117 - 15127 (2021/10/25)
A visible-light-driven photoredox-catalyzed nonaqueous oxidative C-N cleavage of N,N-dibenzylanilines to 2° amides is reported. Further, we have applied this protocol on 2-(dibenzylamino)benzamide to afford quinazolinones with (NH4)2S2O8 as an additive. Mechanistic studies imply that the reaction might undergo in situ generation of α-amino radical to imine by C-N bond cleavage followed by the addition of superoxide ion to form amides.
Iron(III) chloride/diorganyl diselenides promoted regio-and stereoselective cyclization of ortho-alkynylanilides: Synthesis of (Z)-4-(chalcogen) methylenebenzoxazines
Stein, Andre L.,Bilheri, Filipe N.,Back, Davi F.,Zeni, Gilson
, p. 501 - 508 (2014/05/20)
Intramolecular 6-exo-dig cyclization of ortho-alkynylanilides has been employed in a regioand stereoselective synthesis of (Z)-4-(chalcogen)- methylenebenzoxazines. Several reaction parameters were screened for the efficient cyclization of orthoalkynylani
Silver-catalyzed cascade cyclization-stannylation of o-alkynylaniline derivatives with 2-tributylstannylfuran: An efficient synthesis of (3-indolyl)stannanes
Liu, Jun,Xie, Xin,Liu, Yuanhong
supporting information, p. 11794 - 11796 (2013/12/04)
A straightforward synthesis of (3-indolyl)stannanes through silver-catalyzed cyclization-stannylation of N-electron-withdrawing group-substituted o-alkynylanilines in the presence of 2-tributylstannylfuran is developed. This method offers several advantages such as no requirement of additional ligands, high efficiency and a wide reaction scope.