1048964-07-3

Basic information

• Product Name: 1-(6-phenylnaphthalen-2-yl)ethanone
• Synonyms: 1-(6-phenylnaphthalen-2-yl)ethanone
• CAS NO: 1048964-07-3
• Molecular Weight: 246.309
• Mol File: 1048964-07-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(6-phenylnaphthalen-2-yl)ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(6-phenylnaphthalen-2-yl)ethanone(1048964-07-3)
• EPA Substance Registry System: 1-(6-phenylnaphthalen-2-yl)ethanone(1048964-07-3)

Safety Data

• Hazardous Substances Data: 1048964-07-3(Hazardous Substances Data)

Upstream product

• 1279101-95-9 C₁₆H₁₉O₅P 
• 98-80-6 phenylboronic acid 
• 3900-45-6 6-methoxy-2-acetylnaphthalene 
• 5123-13-7 5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane 
• 3262-89-3 triphenylboroxine 
• 63256-69-9 6-acetyl-2-naphthyl acetate 

Downstream Products

• 1075754-25-4 C₁₈H₁₄O₂ 

Relevant articles and documents

Nickel-catalyzed cross-coupling of aryl phosphates with arylboronic acids

The Suzuki-Miyaura cross-coupling of aryl phosphates using Ni(PCy 3)2Cl2 as an inexpensive, bench-stable catalyst is described. Broad substrate scope and high efficiency are demonstrated by the syntheses of more than 40 biaryls and by constructing complex organic molecules. The poor reactivity of aryl phosphates relative to aryl halides is successfully employed to construct polyarenes by selective cross-coupling using Pd and Ni catalysts.

Biaryl construction via Ni-catalyzed C-O activation of phenolic carboxylates

Biaryl scaffolds were constructed via Ni-catalyzed aryl C-O activation by avoiding cleavage of the more reactive acyl C-O bond of aryl carboxylates. Now aryl esters, in general, can be successfully employed in cross-coupling reactions for the first time.