104944-25-4

Basic information

• Product Name: Phosphonic acid, [(R)-hydroxyphenylmethyl]-
• CAS NO: 104944-25-4
• Molecular Formula: C7H9O4P
• Molecular Weight: 188.12
• Mol File: 104944-25-4.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, [(R)-hydroxyphenylmethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, [(R)-hydroxyphenylmethyl]-(104944-25-4)
• EPA Substance Registry System: Phosphonic acid, [(R)-hydroxyphenylmethyl]-(104944-25-4)

Safety Data

• Hazardous Substances Data: 104944-25-4(Hazardous Substances Data)

Upstream product

• 85185-11-1 diethyl [(R)-hydroxy(phenyl)methyl]phosphonate 
• 741292-48-8 di-(1R,2S,5R)-menthyl benzoylphosphonate 
• 98-88-4 benzoyl chloride 
• 74038-34-9 diallyl benzylphosphonate 
• 18406-56-9 Bis(trimethylsilyl) benzylphosphonate 
• 1499-19-0 benzylphosphonic dichloride 
• 1080-32-6 O,O-diethyl benzylphosphonate 
• 3277-27-8 diethyl benzoylphosphonate 
• 536739-07-8 diallyl (R)-α-hydroxybenzylphosphonate 
• 211134-54-2 ((R)-Hydroxy-phenyl-methyl)-phosphonic acid bis-[(3aR,5R,6S,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl] ester 
• 119552-91-9 (R)-(+)-dibenzyl hydroxy(phenyl)methanephosphonate 
• 100-52-7 benzaldehyde 
• 211134-57-5 (-)-di-[(1R,2S,5R)-menth-2-yl] (α-hydroxybenzyl)phosphonate 

Downstream Products

• 104944-34-5 (R)-2-tert-Butoxycarbonylamino-propionic acid (R)-(bis-benzhydryloxy-phosphoryl)-phenyl-methyl ester 
• 104944-40-3 (R)-2-Amino-3-methyl-butyric acid (R)-phenyl-phosphono-methyl ester 
• 104944-39-0 (R)-2-Amino-propionic acid (R)-phenyl-phosphono-methyl ester 
• 104944-35-6 (R)-2-tert-Butoxycarbonylamino-3-methyl-butyric acid (R)-(bis-benzhydryloxy-phosphoryl)-phenyl-methyl ester 
• 89865-26-9 (Hydroxy-phenyl-methyl)-phosphonic acid dibenzhydryl ester 
• 119552-91-9 (R)-(+)-dibenzyl hydroxy(phenyl)methanephosphonate 

Relevant articles and documents

Double asymmetric induction as method for the synthesis of chiral organophosphorus compounds

New examples of multistereoselective syntheses of organophosphorus compounds are described.

New method for the asymmetric reduction of ketophosphonates

Chiral reducing reactants were prepared from lithium, sodium, or tetrabutylammonium borohydrides and (S)- or (R)-tartaric acids. Copyright Taylor & Francis Group, LLC.

Organic catalysis of phospha-aldol condensation

Phospha-aldol reaction of dialkylphosphites with carbonyl compounds is catalyzed by cinchonine alkaloids and thier modified derivatives to give optically active hydroxyphosphonates. The use of diastereomeric pairs of alkaloids allowed obtaining both optic