105057-95-2

Basic information

• Product Name: CdBr₂(P(C₆H₅)3O)2
• CAS NO: 105057-95-2
• Molecular Weight: 828.799
• Mol File: 105057-95-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: CdBr₂(P(C₆H₅)3O)2(CAS DataBase Reference)
• NIST Chemistry Reference: CdBr₂(P(C₆H₅)3O)2(105057-95-2)
• EPA Substance Registry System: CdBr₂(P(C₆H₅)3O)2(105057-95-2)

Safety Data

• Hazardous Substances Data: 105057-95-2(Hazardous Substances Data)

Upstream product

• 791-28-6 Triphenylphosphine oxide 
• 7789-42-6 cadmium(II) bromide 

Relevant articles and documents

A thermochemical study involving adducts MX2*P(C6H5)3O (M = Zn, Cd, Hg; X = Br, I)

The standard molar enthalpy ΔrH0m of the reaction: MX2(s) + 2P(C6H5)3O(s) = MX2*2P(C6H5)3O(s), where M = Zn, Cd, Hg and X = Br, I (except HgI2) was obtained through the determination of the enthalpy of dissolution of the metal halides, ligand, and adducts in calorimetric solvent, giving the values: -(69.92 +/- 1.10); -(63.02 +/- 0.39); -(16.02 +/- 0.56); -(30.55 +/- 0.87); and -(16.48 +/- 1.14) kJ/mol, for the sequence of halides: ZnBr2, ZnI2, CdBr2, CdI2, and HgBr2.The standard molar enthalpies of formation were also determined: -(622.2 +/- 6.8), -(495.0 +/- 6.3), -(556.2 +/- 6.5), -(457.8 +/- 7.1), and -(411.1 +/- 6.4) kJ/mol, for the above sequence as well as the standard enthalpies of reaction: ΔdH0m for MX2*2P(C6H5)3O(s) = MX2(s) + 2P(C6H5)3O(g); and ΔlattH0m for MX2*2P(C6H5)3O(s) = MX2(g) + 2P(C6H5)3O(g).The mean enthalpy of dissociation of the metal-oxygen bond, (M-O), was also estimated and compared with other results.