1051942-01-8

Basic information

• Product Name: (2R,3R,4S,5S)-5-(Benzyloxy)-2-(hydroxymethyl)piperidine-3,4-diol
• Synonyms: (2R,3R,4S,5S)-5-(Benzyloxy)-2-(hydroxymethyl)piperidine-3,4-diol
• CAS NO: 1051942-01-8
• Molecular Weight: 253.298
• Mol File: 1051942-01-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3R,4S,5S)-5-(Benzyloxy)-2-(hydroxymethyl)piperidine-3,4-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,4S,5S)-5-(Benzyloxy)-2-(hydroxymethyl)piperidine-3,4-diol(1051942-01-8)
• EPA Substance Registry System: (2R,3R,4S,5S)-5-(Benzyloxy)-2-(hydroxymethyl)piperidine-3,4-diol(1051942-01-8)

Safety Data

• Hazardous Substances Data: 1051942-01-8(Hazardous Substances Data)

Upstream product

• 1051941-93-5 (4S,5R)-4-((S)-2-Azido-1-(benzyloxy)ethyl)-2,2-dimethyl-5-vinyl-1,3-dioxolane 

Downstream Products

• 19130-96-2 1,5-dideoxy-1,5-imino-D-glucitol 

Relevant articles and documents

New access to 1-deoxynojirimycin derivatives via azide-alkene cycloaddition

(Chemical Equation Presented) The synthesis of 1-deoxynojirimycin (DNJ) derivatives is described from D-glucono-δ-lactone. The DNJ derivatives were obtained via a sequence that included a stereoselective intramolecular Huisgen reaction, decomposition to an aziridine, and its subsequent reaction with a nucleophile. Minimization of allylic strain in the transition state accounts for the stereoselectivity of the cycloaddition reaction.