105198-51-4

Basic information

• Product Name: (Z)-(12R,13R)-12-(tert-Butyl-diphenyl-silanyloxy)-13-hydroxy-octadec-9-enoic acid methyl ester
• CAS NO: 105198-51-4
• Molecular Weight: 566.897
• Mol File: 105198-51-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-(12R,13R)-12-(tert-Butyl-diphenyl-silanyloxy)-13-hydroxy-octadec-9-enoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-(12R,13R)-12-(tert-Butyl-diphenyl-silanyloxy)-13-hydroxy-octadec-9-enoic acid methyl ester(105198-51-4)
• EPA Substance Registry System: (Z)-(12R,13R)-12-(tert-Butyl-diphenyl-silanyloxy)-13-hydroxy-octadec-9-enoic acid methyl ester(105198-51-4)

Safety Data

• Hazardous Substances Data: 105198-51-4(Hazardous Substances Data)

Upstream product

• 98050-12-5 tert-Butyl-((2R,3R)-5-methoxy-2-pentyl-tetrahydro-furan-3-yloxy)-diphenyl-silane 
• 88462-46-8 (8-carboxyoctyl)triphenylphosphonium bromide 
• 603-35-0 triphenylphosphine 
• 186581-53-3 diazomethane 
• 98050-08-9 (2R,3R)-5-Methoxy-2-((E)-pent-1-enyl)-tetrahydro-furan-3-ol 
• 105229-01-4 (2S,3R)-3-Hydroxy-5-methoxy-tetrahydro-furan-2-carbaldehyde 
• 98050-10-3 (2R,3R)-5-Methoxy-2-pentyl-tetrahydro-furan-3-ol 
• 41059-02-3 9-bromononanoic acid 

Downstream Products

• 32381-42-3 (-)-vernolic acid 

Relevant articles and documents

SYNTHESIS OF 12(R),13(S)-OXIDO-9Z-OCTADECENOIC (VERNOLIC) AND 13(S)-HYDROXY-9Z,11E-OCTADECADIENOIC (CORIOLIC) ACIDS

(-)-Vernolic acid was prepared enantiospecifically from a readily available carbohydrate precursor and isomerized to (+)-coriolic acid using the methylmagnesium salt of N-cyclohexylisopropylamine.