1053626-36-0

Basic information

• Product Name: phenyl 2-thio-β-D-fructopyranoside
• Synonyms: phenyl 2-thio-β-D-fructopyranoside
• CAS NO: 1053626-36-0
• Molecular Weight: 272.322
• Mol File: 1053626-36-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: phenyl 2-thio-β-D-fructopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 2-thio-β-D-fructopyranoside(1053626-36-0)
• EPA Substance Registry System: phenyl 2-thio-β-D-fructopyranoside(1053626-36-0)

Safety Data

• Hazardous Substances Data: 1053626-36-0(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 99042-47-4 2'-chloroethyl 1,3,4,5-tetra-O-acetyl-β-D-fructopyranoside 

Downstream Products

• 1053268-51-1 2,6-anhydro-1,3,4-tri-O-benzyl-β-D-fructofuranose 
• 38982-46-6 2,6-Anhydro-β-D-fructofuranose 
• 445299-09-2 phenyl 4-O-benzoyl-2-thio-β-D-fructopyranoside 
• 445299-14-9 (2S,3S,4R,5R)-4-Benzyloxy-2-hydroxymethyl-2-phenylsulfanyl-tetrahydro-pyran-3,5-diol 

Relevant articles and documents

New synthesis of 2,6-anhydro-β-D-fructofuranoses, pivotal [2.2.1] bicyclic acetals for the conversion of D-fructose into 2,2,5-trisubstituted tetrahydrofurans

2,6-Anhydro-β-D-fructofuranose derivatives were prepared by a novel tin-promoted 2,5-cyclisation of phenyl 2-thio-β-D-fructopyranosides. They were regioselectively opened by allyltrimethylsilane in the presence of catalytic Sc(OTf)3 to give 2,2,5-trisubstituted tetrahydrofurans in high yields and major α-stereoselectivity.