105417-32-1

Basic information

• Product Name: Benzoic acid, 4-(phenylseleno)-, methyl ester
• CAS NO: 105417-32-1
• Molecular Formula: C14H12O2Se
• Molecular Weight: 291.208
• Mol File: 105417-32-1.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-(phenylseleno)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-(phenylseleno)-, methyl ester(105417-32-1)
• EPA Substance Registry System: Benzoic acid, 4-(phenylseleno)-, methyl ester(105417-32-1)

Safety Data

• Hazardous Substances Data: 105417-32-1(Hazardous Substances Data)

Upstream product

• 106206-61-5 4-(phenylselanyl)benzoic acid 
• 619-44-3 methyl 4-iodobenzoate 
• 645-96-5 Benzeneselenol 
• 1666-13-3 diphenyl diselenide 
• 99768-12-4 4-methoxycarbonylphenylboronic acid 
• 41924-21-4 phenyl tributylstannyl selenide 
• 1126-46-1 Methyl 4-chlorobenzoate 
• 619-42-1 4-methoxycarbonylphenyl bromide 
• 619-45-4 4-methoxycarbonyl aniline 
• 23974-72-3 sodium phenylselenide 

Relevant articles and documents

A general method for the formation of diaryl selenides using copper(I) catalysts

We report a mild, palladium-free synthetic protocol for the cross coupling reaction of aryl iodides and phenyl selenol using 10 mol% CuI/neocuproine, NaOt-Bu or K2CO3 as base, in toluene, at 110°C. Using this protocol, we show that a variety of diaryl selenides can be synthesized in good yields from commercially available aryl iodides.

Trichloroisocyanuric Acid-Promoted Synthesis of Arylselenides and Aryltellurides from Diorganyl Dichalcogenides and Arylboronic Acids at Ambient Temperature

A transition-metal-free method for the synthesis of arylselenides and aryltellurides has been established based on the oxidative cross-coupling between diorganyl dichalcogenides and aryl boronic acids. With trichloroisocyanuric acid as an oxidant, the reaction proceeded smoothly to afford the desired products in 45–97% yields at ambient temperature. Three reaction reagents used in this method are stoichiometric and the oxidation by-product isocyanuric acid can be easily isolated and recovered. Besides of arylboronic acids, aryl trifluoroborates and aryl trihydroxyborates salts are also able to perform this transformation. (Figure presented.).

Method for preparing asymmetric organic selenium ether compounds through metal-free chemical oxidation method (by machine translation)

The method is mild in reaction condition, convenient to operate, high in 1 reaction condition, convenient 2 to operate, high in safety, wide in substrate range, high 2 - 8h in yield, particularly suitable for reaction of various poor 3 electric and sterically hindered arylboronic acid and diselenoxy ether, and capable of finishing most of the reaction 4h. (by machine translation)