105457-29-2

Basic information

• Product Name: (6Z,9Z,11E)-15,15-bis(ethylthio)-13(S)-<(tert-butyldiphenylsilyl)oxy>pentadecatriene
• CAS NO: 105457-29-2
• Molecular Weight: 581.015
• Mol File: 105457-29-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (6Z,9Z,11E)-15,15-bis(ethylthio)-13(S)-<(tert-butyldiphenylsilyl)oxy>pentadecatriene(CAS DataBase Reference)
• NIST Chemistry Reference: (6Z,9Z,11E)-15,15-bis(ethylthio)-13(S)-<(tert-butyldiphenylsilyl)oxy>pentadecatriene(105457-29-2)
• EPA Substance Registry System: (6Z,9Z,11E)-15,15-bis(ethylthio)-13(S)-<(tert-butyldiphenylsilyl)oxy>pentadecatriene(105457-29-2)

Safety Data

• Hazardous Substances Data: 105457-29-2(Hazardous Substances Data)

Upstream product

• 110-53-2 1-Bromopentane 
• 5044-52-0 vinyltriphenylphosphonium bromide 
• 100818-44-8 (E)-4-(tert-Butyl-diphenyl-silanyloxy)-6,6-bis-ethylsulfanyl-hex-2-enal 
• 74-86-2 acetylene 

Relevant articles and documents

Scope and Limitations of the Cuprate-Acetylene-Vinyltriphenylphosphonium Bromide-Aldehyde Reaction: Synthesis of (6Z,9Z)-Heneicosadiene

Syntheses of (6Z,9Z)-heneicosadiene, a component of the sex attractant secretion of the female arctiid moth (Uthetheisa ornatrix), and of triene 6, a useful precursor for the synthesis of (8S)-HETE, are described using a one-pot four-component (cuprate-acetylene-vinyltriphenylphosphonium bromide-aldehyde) reaction.The use of 1-iodo-1-alkenes as an alternative to Normant's alkenylcuprate methodology is demonstrated.